两相溶液法制备有机质子酸掺杂Py-MMA共聚物及-华东理工大学学报.PDF

DOI: 10.14135/j.cnki.1006-3080.20180417001 两相溶液法制备有机质子酸掺杂Py-MMA 共聚物 及其导电与溶解性能研究 1 吴 唯 ， 杨晓格 （华东理工大学，材料科学与工程学院，中德先进材料联合研究中心，上海 200237 ） 摘要：采用4 种有机质子酸为掺杂剂，氯化铁为氧化剂，通过化学氧化法制备了有机质子酸 掺杂聚吡咯（PPy ）。在此基础上，在两相溶液中制备了吡咯- 甲基丙烯酸甲酯（Py-MMA ） 共聚物，研究了掺杂剂含量、氧化剂含量、单体 MMA 含量、反应温度等因素对 Py-MMA 共聚物电导率及溶解性能的影响。结果表明，有机质子酸掺杂PPy 可有效提高PPy 的电导 率。当以对甲苯磺酸作掺杂剂，掺杂剂与Py、氧化剂与Py 单体摩尔比各为 1:3，反应温度 为5℃，反应时间为12h 时，所制得的有机质子酸掺杂PPy 的导电性能最好。与PPy 相比， Py-MMA 共聚物的溶解性能得到明显提高。当 MMA: K S O : Py: TsOH 物质的量之比为 2 2 8 2:3:6:4，反应温度为40 ℃，反应时间4h 时，所制得的Py-MMA 共聚物的溶解性能最佳，其 70℃溶于乙酸乙酯的溶解度为5.56 g，表面电阻率为0.76 cm 。 关键词 有机质子酸；掺杂；PPy ；MMA ；电导率；溶解度 中图分类号：TQ324.8 文献标志码:A Study on Synthesis and Solubility of p(Py-co-MMA) Doped by Organic Protonic Acid in Two-phase Solution WU Wei, YANG Xiaoge (Sino-German Joint Research Center of Advanced Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237) Abstract: PPy(polypyrrole) has been a kind of popular electrical polymer during last few decades, owing to its excellent conductivity. However, it ’s very difficult to process PPy materials. Therefore, enhancing solubility of PPy may improve its process ability. In this paper, PPy was synthesized by chemical oxidation method, 4 kinds of organic protonic acid were used as dopant and FeCl3 was used as oxidant. Several factors which might cause fluctuation of electrical conductivity were researched and analyzed under orthogonal experiments, including type of dopant, reaction temperature, dosage of dopant and oxidant, duration of