地下水混合作用的碳酸钙溶解沉淀效应-地球科学与环境学报-长安大学.PDF

29 1 No. 1 Vol. 29 2 0 0 7 3 　Journal of Earth Sciences and Environment 　 Mar . 2 00 7 钱　会, 连　 , 窦　妍 ( , 71005 ) :, , CaCO 、 3 , , , 。()()()。 , 。 :CaCO ;;;() 3 :P6 1　:A　:1672-6561(2007)0-1 005-5 11 Mixing Effects of Groundwater on CaCO3 Dissolution and Precipitation QIAN Hui, LIAN Jun, DOU Yan (S chool of E nv ironmen ta l S c iences and E ng ineer in g , Ch an g’an Univ ersi ty , X i’an 71005 , Shaan x i, Ch ina) Abstract:The methods of aqueous speciation calculation, pH calculation as well as the calculation of solubility (precipitability)of CaCO in natural w ater were used to study the effects of mixing of groundwater on the dissolution 3 (precipitation)of CaCO . Mixing were made for three groups of natural groundwater, one is the mixing betw een 3 unsaturated (with CaCO )water, the second group is the mixing between supersaturated water, and the last group is 3 the mixing of unsaturated water with supersaturated water. Results show that mixing of natural groundw ater can not only lead to increase the dissolution of CaCO , but also increase the precipitation of CaCO according to the composition 3 3 of the groundwater. Both the mixing dissolution and mixing precipitation can be classified into two kinds, that is an increased mixing dissolution (precipitation)in strict sense and an