纳米CaCO3增强木质基复合材料力学性能研究-中南林业科技大学学报.PDFVIP

第34 卷 第12 期 中 南 林 业 科 技 大 学 学 报 Vol. 34 No. 12 2014 年 12 月 Journal of Central South University of Forestry Technology Dec. 2014 纳米CaCO 增强木质基复合材料力学性能研究 3 何 霄，袁光明，肖罗喜 （中南林业科技大学 材料科学与工程学院，湖南 长沙 4 10004 ） 摘 要：将改性分散后的纳米 CaCO3 加入到木粉和木纤维中，通过添加脲醛树脂，组胚，热压成型，制得木质基 - 纳米 CaCO3 复合材料，利用激光粒度仪、FTIR 及 XRD 表征，并进行力学性能测试与分析。实验表明：经过改 性后的纳米 CaCO3 粒径变小，改性剂可以成功吸附于纳米 CaCO3 表面，当添加纳米 CaCO3 质量分数为 7% 时， 木质基复合材料力学性能提高量最大；其静曲强度、弹性模量及内结合强度分别为29.08 MPa、5 686 MPa 和 0.72 MPa，分别提高了31%，97%，50% 。 关键词：纳米 CaCO3 ；木粉；木纤维；复合材料；力学性能 中图分类号：S781.2 文献标志码：A 文章编号：1673-923X(2014) 12-0155-04 Researches on mechanical properties reinforced wood-based composites with nano-CaCO3 HE Xiao, YUAN Guang-ming, XIAO Luo-xi (School of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, Hunan, China) Abstract: After modified and dispersed, the nano-particles, then were j oined into the wood power and wood fiber, and adding urea formaldehyde resin, group of embryo, and by hot-pressing, then wood-based nano-CaCO3 composites was made out, by using laser particle size analyzer and through represented by XRD and FTIR, the mechanical properties of the composites were tested and analyzed. The results show that the size of nano CaCO3 particle after modified became smaller, the modifier were adsorbed on the surface of nano CaCO3 successfully, when the mass fraction of nano-CaCO3 after adding was 7%, the improvement of mechanical properties for wood power composite was the largest, to wood flour-nano CaCO3 composite materials，the static bending strength, the modulus of elasticity and intensity of inte