减缩剂对水泥石体积稳定性的影响及其机理-硅酸盐学报.PDFVIP

· 478 · 硅 酸 盐 学 报 2010 年 第 38 卷第 3 期 硅 酸 盐 学 报 Vol. 38 ，No. 3 2 0 1 0 年 3 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY March ，2010 减缩剂对水泥石体积稳定性的影响及其机理 吴浩，姚燕，王玲 ( 中国建筑材料科学研究总院，绿色建筑材料国家重点实验室，北京 100024) 摘 要：针对水泥混凝土结构在服役期间经历干旱、降雨等自然现象的交替作用所产生的体积变化，选择在温度、湿度交变[35 ℃，相对湿度(relative humidity) Rh = 30% ；20 ℃，Rh = 100%]试验条件下评价减缩剂对水泥石体积稳定性的影响，并采用核磁共振和压汞仪分析其机理。 结果表明：减缩 剂通过提高水泥石在温度、湿度交变环境的水化程度、增大水化硅酸钙凝胶的聚合程度，同时降低水泥石的可逆、不可逆收缩及最大长度变化，减小 在严酷干燥条件的干缩值及潮湿环境的湿胀值，提高在恶劣自然环境保持较高体积稳定性的能力。 关键词：水泥石；减缩剂；体积稳定性；机理 中图分类号：TU502 文献标志码：A 文章编号：0454–5648(2010)03–0478–08 INFLUENCE OF SHRINKAGE REDUCING ADMIXTURE ON VOLUME STABILITY OF CEMENT PASTE AND ITS MECHANISM WU Hao，YAO Yan，WANG Ling (China Building Materials Academy, State Key Laboratory of Green Building Materials, Beijing 100024, China) Abstract: Capability of cementitious materials to resist cracks was decided by its volume stability under different conditions. Different temperature and humidity parameters (35 ℃, relative humidity Rh = 30%; 20 ℃, Rh = 100%) were selected to simulate different envi- ronment conditions, the influence of shrinkage reducing admixture on volume stability of cement paste containing was studied, and the mechanism of shrinkage reducing admixture action was researched by the nuclear magnetic resonance and mercury intrusion po- rosimetry. The results show that the volume stability of cement paste under alternating temperature and humidity is strengthened through improving the hydration process, that is, enhancing the hydration degrees for cement and polymerization degrees for calcium silicate hydrate, changing the structure o