新颖表面结构的脲醛树脂-聚丙烯酰胺复合微球的制备研究Preparation.PDFVIP

2008 年第 66 卷 化 学 学 报 Vol. 66, 2008 第 11 期, 1293～1300 ACTA CHIMICA SINICA No. 11, 1293～1300 ·研究论文· 新颖表面结构的脲醛树脂-聚丙烯酰胺复合微球的制备研究 孙莉峰 张 颖* 吴华涛 房 喻 胡道道 (应用表面与胶体化学教育部重点实验室 陕西师范大学化学与材料科学学院 西安 710062) 摘要 将高分子微凝胶模板法应用于制备脲醛树脂[Urea-formaldehyde resin (UF Resin)]-聚丙烯酰胺[Polyacrylamide (PAM)]有机-有机复合微球材料. 以 PAM 高分子微凝胶为模板, 通过控制甲醛和尿素的缩聚反应在反相悬浮体系中进 行, 制备得到了具有新颖表面形貌的脲醛树脂-聚丙烯酰胺[UF Resin/PAM]有机-有机复合微球, 利用扫描电子显微镜 (SEM)、热重分析(TGA)、红外(FT-IR)等手段对复合微球进行了表征. 实验结果表明, 复合微球的表面形貌与甲醛和尿 素溶液的 pH 值、甲醛和尿素溶液的浓度、甲醛和尿素的摩尔比、模板的组成等因素有关. 可以预期, 本研究方法将为 制备具有特异表面形貌的有机-有机复合微球材料提供了一条有效的途径. 关键词 微凝胶; 脲醛树脂; 复合微球; 模板法 Preparation of Urea-formaldehyde Resin/Polyacrylamide Composite Microspheres with Novel Surface Structures SUN, Li-Feng ZHANG, Ying∗ WU, Hua-Tao FANG, Yu HU, Dao-Dao (Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Materials Science, Shaanxi Normal University, Xian 710062 ) Abstract The application of a polymer microgel template method was extended for the preparation of urea-formaldehyde resin and polyacrylamide organic/organic composite microspheres. The UF Resin/PAM composite microspheres with novel surface morphology were prepared via polycondensation between form- aldehyde and urea in the inverse suspension system using PAM microgels as a template. The prepared com- posite microspheres were characterized by scanning electron microscopy, thermogravimetric analysis, and Fourier transform infrared s