基于Co3O4和Si的新型复合材料及其储锂性能测试-凝聚态物理专业论文.docxVIP

湘潭 湘潭大学硕士毕业论文 II II 合结构材料进行了储锂性能的测试，其结果表明：制备的复合结构具有很好的循 环稳定性，并且在变 C 循环的条件下，这种复合物也很稳定。突出显示出了这 种复合结构作为锂电的所不可比拟的优势。 制备 Si/Graphene 的夹层结构。第一，在原有的 Hummers 方法上制备出了氧 化石墨烯(GO)。然后称取一定量的 GO 溶解在去离子水中，制备出一定浓度的 GO 水溶液。第二，称取商用的直径为 30 nm 的 Si 颗粒均匀地分散在去离子水中， 得到一定浓度的 Si 溶液。第三，采用真空抽滤的方法先抽一层 GO，然后在其上 面抽一层 Si 层。多次进行真空抽滤以抽取不同层的复合物。第四，将制备好的 Si/Graphene Oxide 复合物浸入到 HBr 酸中把 GO 还原为 G，我们得到了最后的产 物 Si/Graphene 复合物。通过采用 Raman, EDS 和 SEM 等表征手段，证明了我们 成功的制备了叠状夹层的 Si/Graphene 复合物。最后，我们进行了储锂性能的测 试。最终结果表明，我们设计的这种复合物显示了很好的储锂性能，有望在工业 上进行大规模的实际生产。 关键词：Co3O4/Si 复合纳米线结构；Co3O4/Graphene 复合材料；Si/Graphene 复 合材料；锂离子电池 III III Abstract During the past few decades, scientists from all over the world are energetically searching for new green energy sources and/or energy storage materials due to the energy crisis and the concomitant environmental problems, all of which are induced by the rapid society development. The rechargeable lithium ion battery, which is developed in the 20th century, has been widely used in the portable phones, portable computers, and cameras and so on owning to its lots of outstanding merits such as the higher capacity, the higher voltage and the long life. Recently, most of the traditional batteries have been substituted by the rechargeable lithium ion batteries. In addition, high capacity rechargeable lithium ion batteries have been used in the electro-car and are expected to be the main energy source of the car in 21st century. Among the electrode of the lithium ion battery, the transitional metal oxide, cobalt oxide, for example, have attracted wide research interests because of its high theoretical capacity. Also, owning to the highest known theoretical charge capacity of 4009 mAh g-1, silicon has received focus from researchers all over the world. In this graduation thesis, we have conducted the fabrication, characterization and the electrochemical test of two cobalt oxide based and one silicon based composites. We have devoted ourselves to find the highest output of cobalt oxide an