基于半互穿网络结构含氟聚酰亚胺增强Nafion复合质子交换膜材料的研究-材料科学与工程；材料学专业论文.docxVIP

Nation@2 Nation@2 12为基体，偶氮二异丁腈(AIBN)为引发剂，在制膜过程中引发乙 烯基交联，并和Nation@212形成半互穿网络结构的复合膜。研究了复合膜 的热稳定性、含水率、尺寸稳定性、抗氧化稳定性、机械性能和质子传导 率等。结果表明，与纯Nation@212膜相比，复合膜具有优异的机械性能以 及尺寸稳定性能。复合膜的拉伸强度在39．0．80．0 1VIPa之间，并随着VFPI．X 中可交联基团含量的增大而增大。复合膜的质子传导率在2．O×1 O～． 8．9×10五Sem’1之间，并随着VFPI。X含量的增大而降低。 以含乙烯基的可交联聚酰亚胺(VFPI)和Nation@212为基体，AIBN为 引发剂，乙烯基类单体(烯丙基磺酸钠，丙烯酸，对苯二乙烯，1．乙烯基咪 唑)为交联剂，在成膜过程中，原位引发乙烯基类交联剂和可交联聚酰亚胺 聚合，制备得到含半互穿网络结构的复合膜材料。研究了不同交联剂对复 合膜的热稳定性、含水率、尺寸稳定性、抗氧化稳定性、机械性能和质子 传导率等的影响。基于碱性较强的交联剂所制备的VCM．VI的拉伸强度最 高，为51．2 MPa；以乙烯基磺酸钠为交联剂的VCM．SAS的热稳定性最高， 其磺酸基分解温度为400℃。复合膜的质子传导率在1．9×10～．9．9×10。2 Sem。1 之间。在VFPI．20含量一定的情况下，复合膜的质子传导率与加入的交联 剂有关，含导电质子的交联剂所制备的复合膜的导电率较大。VCM．SAS的 导电率最大，在1000C时为9．9×10之Scm～。 关键词：含氟聚酰亚胺，半互穿网络，Nation⑧，交联，质子交换膜 The The composite proton exchange membrane based on semi—interpenetrating polymer network of fluorine．containing polyimide and Nation@ Abstract Proton exchange membrane fuel cells(PEMFC)ore one of the most promising alternative energy source because of their high power density，no noise，low working temperature， environmental friendly，etc．It can convert the chemical energy from the electrochemical reaction of the hydrogen and oxygen into electrical energy directly．Up till now， perfluorosulfonic acid membranes have been the widely used proton exchange membranes (PEMs)，either in practical systems or academics．However，they still have disadvantages of high cost，high methanol permeability and reduced proton conductivity at high temperatures which limit their further applications especially in high temperature fuel cell operation． Therefore，extensive attempts have been performed to the preparation of PEMs by polymers with low cost through sulfonation or adulterating inorganic proton conductors． A series of reinforced composite membranes as proton exchange membranes were prepared from Nation@2 1 2 and crosslinkable fluorine—containing polyimides(FPI)．FPI Was prepared from the polymerization of 4，4-(hexafluoroisopropylidene)diphthalic anhydride(6FDA)， 2，2’-bis(trifluoromethyl)