基于差分吸收光谱技术的大气气体监测的研究-光学工程专业论文.docxVIP

重庆大学硕士学位论文 重庆大学硕士学位论文 英文摘要 ABSTRACT Since applied in atmosphere monitoring at the end of 1970、S，differential optical absorption spectroscopy(DOAS)havemade quietgreatprogress．、Vitll advantages ofits lower equipment expenses and excellent monitoring capability,DOAS technique will own broad prospect at home． The article mainly includes the design of experimental set and concentration retrieve arithmetic．As DOAS technique is a kind of weak light detecting technology,it is the key to increase the SNR(Signal—to-Noise)of spectral signal．So the article introduces in details the design of the experimental set at the first work．The other work iS to design the method of the retrievaI of concentrations of the interest gases．Because of change ofthe temperature and atmosphere pressure，misaiignment arises between the measured spectra and the reference．The misaiignment Will make the results of the retrieval wrong．So the analysis of calibration is emphasis in the article． 111e article provides the demonstrations of the light soBrcc．transmitting／receiving set and homochromor．The whole W0rk iS to fix on也e sets and select也e parameters of them．At the end of the design of sets，a whole set is achieved by assembling the three main parts． As nonlinear parameters introduced in process of血e caIibration of spectral misalignment，the linear and nonlinear least square methods are used in the retrieval procedure in the article．h the article，the mixed least squared method defined MLSM method．Detailed analysis ofthe method and the brought by the method is performed．Three conclusions are attained among the numerical simulations：First，the LSM method is the optimum method to retrieve the conccn廿ations ofthe gases．Second， the MLSM method does well in calibrating the misalignment．啊】ird．only if the SNR is higher，the results of the retrieve Can be attained truly,and the errors are in the permitted ra