基于半刚性温敏性无规共聚物的合成与表征-高分子化学与物理专业论文.docxVIP

湘潭大学硕士学位论文 湘潭大学硕士学位论文 II II Abstract Due to reversible property changes in response to temperature, thermoresponsive polymers have attracted considerable research interests. However, the main-chains of these synthesized thermoresponsive polymers are mostly flexible and some of the thermoresponsive natural polymer and its derivatives segment with semi-rigid structure were difficult to molecular design and synthesis, all those hinder further research of these polymers. Mesogen-Jacketed Lliquid Crystal Polymer (MJLCP) is a typical semi-rigid synthesized polymer, but it is hardly water-solubled. Therefore, how to design and synthesize a novel polymer based on MJLCPs exhibited thermoresponsive property is very significance. Three novel thermoresponsive copolymers with the semi-rigid were synthesized via random copolymerization, and we focus on the body and solution properties. At first, synthesized random copolymer poly{{2.5-bis[(4-methoxyphenyl) oxycarbonyl]styrene}-co-bis-(N-hydroxyethylpyrrolidone)2-vinylterephthalate} (P(MPCS-co-NHEPVTA)), and investigated the body and solution properties of copolymers. The copolymers showed only one glass transition. And the results were consistent with our theory judgments: different MPCS content of copolymers have shown character of liquid crystalline. With the MPCS content increased copolymers the lower critical solution temperature (LCST) decreased evidently. The copolymers were almost insoluble in water when the content of MPCS more than 4%. Synthesized random copolymer poly{styrene-co-{2.5-bis[(4-methoxyphenyl) oxycarbonyl]styrene}(P(St-co-NHEPVTA)) and investigated the body and solution properties of copolymers. The copolymers showed only one glass transition. When the content of St more than 20%, the copolymer not showed liquid crystalline. With the St content increased copolymers LCST decreased evidently. The copolymers were almost insoluble in water When the content of PS more than 30%. Last, semi-rigid thermorespo