便携式X荧光仪检出限影响因素的研究.PDF

第41 卷 第1 期 核 技 术 Vol.41, No.1 2018 年1 月 NUCLEAR TECHNIQUES January 2018 便携式X 荧光仪检出限影响因素的研究 杜海燕 赖万昌 石希瑜 陈 诚 胡 燕 赵 瑞 （成都理工大学 成都 610059 ） 摘要 讨论了便携式能量色散型X 荧光仪检出限受背景扣除方法、管电压与管电流的影响。采用空白样扣本 底法、线性本底扣除法、斯托林斯基法(Sterlinski)三种方法扣本底，试验了与之适宜的管电压与管电流范 围，比较了三种方法的优缺点。检出限与测定限存在一定的对应关系，利用检出限得到测定限，对低含量的 样品进行了定量的分析。为降低检出限值和更准确地测量低含量金属元素在背景扣除方法、测量条件等方面 的选择提供参考。 关键词 X 荧光仪，检出限，本底扣除，管电压，管电流 中图分类号 TL99 DOI: 10.11889/j.0253-3219.2018.hjs.41.010202 Influence factor of the detection limit of portable X-ray fluorescence instrument DU Haiyan LAI Wanchang SHI Xiyu CHEN Cheng HU Yan ZHAO Rui (Chengdu University of Technology, Chengdu 610059, China) Abstract [Background] The study of the detection limit of X-ray fluorescence instrument is of great significance, as it is widely used in the analysis of low content elements because of its excellent performance. [Purpose] To reduce the detection limit and measuring low content of metal elements more accurately, we provided reference for the choice of background subtraction methods and measurement conditions, etc. [Methods] This paper studied the influence factors for the detection limit of the portable X-ray fluorescence instrument, such as background subtraction method, tube voltage and tube current. Blank sample-, linear- and Sterlinski- background subtraction methods were used to subtract the backgrounds and the suitable tube voltage and tube current range we