基于导电聚合物的电致变色器件的制备与性能研究-材料学专业论文.docxVIP

dopant dopant and emulsifier,anunonium persulfate as oxidant through in-situ emulsion polymerization to prepare polyaniline-based emulsion,which was used to prepare the polyaniline film by spin-coating．The film-forming property of PANl was adjusted by using different types and content of polyvinyl alcohol during the in—situ emulsion polymerization process．It was found that PVA1 750+50 Was a good film-forming additive with an addition of 2．8％，resultly a polyaniline film present a well film-forming properties and good electrochromic properties· Titanium dioxide sol was prepared by using tetrabutyl titanate as the precursor via sol‘gel method．The different layers of titanium dioxide films were prepared by dip—coating method，and the resulted films were characterized by XRD，SEM，uv,cyclic voltammetry and SO on．Results show that the number of titanium dioxide films is in 30 to 60 layer．Besides，the typical anatase titanium dioxide crystal was formed after heat．treated at 500℃．which had the thickness of about 200 nln with the uniform particle size diameter of about 1 0·20 nm．The films had strong ion storage capacity,steady extraction and embedding rates of lithium‘ion，suitably used as the ion storage layer． The gel electrolyte with PMMA—based system with a conductivity of 1 0‘3S／cm and the optical transmittance more than 85％Was prepared，which Was suitable used as the electrolyte of electrochromic device．In addition，the symmetrical structure electrochromic device(SSECD) ¨ ASECD ASECD was 43．3--nearly about twice of SSECD．Meanwhile,ASECD took Oil reversible color variation among yellow(-I．4 V)，green(oⅥand blue(1．4 V)，and had faster coloring／fading response time(0．8 s)，but its lifetime was little less than that of the SSECD，and need a further improvement． Moreover,a flexible electrochromic device was explorated and studied，and some preliminary results were obtaincd． Key words：Polyaniline,Titanium dioxide，All solid-state electrochromic devices，Responsive time IIl 第1章绪论 第1章绪论