磁性纳米固体超强酸的制备及合成松香甘油酯的研究-林产化学与工业.PDF

24 Vol.24 Supplement 2004 8 Chemistry and Industry of Forest Products Aug. 2004 贾庆明, 王亚明, 陕绍云 ( 昆明理工大学生物与化学工程学院, 云南 昆明650224) JIA Q M 2- : - SO / TiO - Fe O , , 4 2 3 4 2- SO /T iO - Fe O : Ti Fe 4 2 3 4 301, 1.5 mol/L H SO ,450 3 h I T EM 2 4 , Hammett : ; ;; :TQ351. 471; TQ426 :A :0253- 2417(2004) S0- 0065- 04 P EPA ATION OF MAGNETIC NANOMETE SOLID SUPE ACID AND SYNTHESIS OF OSIN GLYCE IDE JIA Qing-ming, WANG Ya-ming, SHAN Shao-yun ( I nsti tute of B iolog ical and Chem ical Eng ineer ing , K unmi ng Un iv er si ty of Science and Techology , K unm ing 650224, Chi na) 2- Abstract: The magnetic nanometer solid superacid SO /T iO-Fe O was prepared by sol-gel method, and its 4 2 3 4 catalytic activity on reaction between rosin acid and glycerol was examined under different preparing conditions. T hus, ratio of Ti and Fe ( 301) , soaking the magnetic nanometer powder in 1. 5 mol/L H SO and calcining at 450 2 4 for 3 h were the optimum preparing conditions. The structure of the catalyst was characterized by I and T EM.