燃烧放热对准东煤成灰过程中钠盐释放的影响.PDF

第46卷 第4期 燃摇 料摇 化摇 学摇 学摇 报 Vol.46 No.4 2018年4 月 Journal of Fuel Chemistry and Technology Apr. 2018 燃烧放热对准东煤成灰过程中钠盐释放的影响 * 余圣辉,张摇 成 ,张小培,周安鹂,许摇 豪,方庆艳,陈摇 刚 (华中科技大学 煤燃烧国家重点实验室,湖北 武汉摇 430074) 摘要:选取典型的准东煤五彩湾煤为研究对象,在马弗炉内制备400-1200益的燃烧灰和再热灰,采用K型热电偶测量燃烧过 程中样品表面温度,通过XRF、XRD分析获得灰的成分和结晶形式,取部分灰样逐级萃取,通过微波消解及电感耦合等离子体 质谱仪(ICP鄄MS),获得灰中钠的赋存特性。 结果表明,燃烧和再热灰在成分和晶体形式上差异显著,再热灰钠含量明显高于 燃烧灰且灰熔点偏低;随着温度升高灰中钠盐总量明显减少,其中,水溶钠、醋酸铵溶钠迅速减少,而盐酸溶钠含量先增加后 减少,不可溶钠增加,释放的钠以可溶钠为主;加热温度和时间影响钠的释放,燃烧反应放热导致煤粉表面温度超过环境温度 200 益以上,是钠盐过多释放的主要原因。 关键词:准东煤;钠释放;灰成分;燃烧反应 中图分类号:TQ536.1摇 摇 摇 摇 文献标识码:A Effect of combustion heat on release and transformation of the sodium during Zhundong coal ash鄄forming process * YU Sheng鄄hui,ZHANG Cheng ,ZHANG Xiao鄄pei,ZHOU An鄄li, XU Hao,FANG Qing鄄yan,CHEN Gang (State Key Laboratory of Coal Combustion,Huazhong University of Science and Technology,Wuhan摇 430074,China) Abstract:As a typical Zhundong coal,Wucaiwan coal was chosen as the object of the investigation. The combustion ash with coal sample and the reheated ash with ashing sample at 400 益 were prepared in a muffle furnace. K鄄type thermocouple wasused to measure the temperature,XRF andXRD were used to investigate the composition of ash,and the sequential chemical extraction was used to examine the modes of occurrence of Sodium. The results show that the combustion ash and the reheated ash have marked differences in composition and melting points,sodium content in the reheated ash ishigher than that in the combustion ash and the melting temperature of the reheated ash islower than that in the combustion ash. With the increase of temperature,the total content of sodiu