载铁活性炭对水中草甘膦吸附性能研究.PDF

中国环境科学 2011,31(2) ：239~244 China Environmental Science 载铁活性炭对水中草甘膦吸附性能研究 谢 明,徐炎华* (南京工业大学环境学院,江苏 南京 210009) 摘要：通过浸渍-焙烧法制备载铁活性炭,并用 SEM 电镜分析了载铁活性炭表面形态,研究了载铁活性炭(Fe-AC)对草甘膦溶液的吸附等温 线和吸附动力学,并分析了各种影响因素对载铁活性炭吸附性能的影响.实验表明,Freundlich 方程可以对 Fe-AC 草甘膦吸附等温线进行很 好拟合,最大吸附量约为 5.8mmol/g;其吸附动力学过程用 Lagergren 方程拟合,吸附速率常数在 0.088min- 1 左右,且随着温度的升高逐渐减小. 根据 Kannan Sundaram 颗粒内扩散模型拟合,颗粒内扩散速率常数 k - 1/2 p 大于 10mg·min /g,并随着起始温度的升高而减小. 由于草甘膦的存 在形态和 Fe-AC 材料表面性质的变化,AC-Fe 对草甘膦的吸附能力随水溶液的 pH 升高而降低.NaCl 的存在产生拮抗效应使得 Fe-AC 对 草甘膦的吸附容量大大下降,随着NaCl 浓度增加至 4g/L 后,盐析效应开始占主导地位,使得 Fe-AC 的吸附容量略有增加; 由于草甘膦分子的 空间位阻效应和亚磷酸根与载铁活性炭表面形成较强的络合物,使得随亚磷酸根浓度的升高 Fe-AC 对草甘膦的吸附量持续下降. 关键词：吸附；草甘膦；载铁活性炭 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2011)02-0239-06 * Glyphosate adsorption by ferric supported active carbon. XIE Ming, XU Yan-hua (College of Environment, Nanjing University of Technology, Nanjing 210009, China). China Environmental Science, 2011,31(2)：239~244 Abstract ：Ferric supported active carbon was prepared by impregnation-calcination method and the characteristics of its surface were investigated by scanning electron magnification (SEM), and both adsorption isotherm and adsorption kinetics of Fe-AC were studied. The effects of different factors on the adsorption process were also studied. Freundlich equation fitted well to supported ferric active carbon adsorption isotherm, the maximum adsorption capacity was 5.8mmol/g; and the adsorption kinetics was fitted well by Lagergren equation, so adsorption rate constant can be calculated out 0.088min- 1 that can decrease with the temperature increase. According to Kannan Sundaram internal diffusion m