碱矿渣偏高岭土复合胶凝材料初步研究-材料学专业论文.docxVIP

浙江人学硕}学位论文Abstract 浙江人学硕}学位论文 Abstract Alkali activated cement has become olle of the active investigated field in cemetitiou materials for its outstanding merits like high strength，fast strength development，excellent durability and resource saving superiority and so on． Alakli—slag—metakaolin composite cement(M—AAS)，made from slag，metakaolin and alkali，is a cemenfitious material by mixing geopolymer and alkali activated slag cement．Through strength and shrinkage test,and XRD，DTA and SEM analysis， strength，shrinkage and erosion resistant properties of M—AAS were all preliminarily studied and relative mechanisms were discussed also．The results indicated： The shrinkage of M—AAS Was comparatively high．Most of the shrinkage developped at the first fourteen days．The shrinkage increased rapidly within 24 hours， and inclined tO stay steadily after 14 days though the shrinkage value Was still high comparatively at that time．The shrinkage value of M·AAS associated with the ratio of Ca to Si in the raw materials．The hiigher the ratio Was．the bigger the shrinkage went，and vice versa．The relationship between the ratio of Ca to Si with shrinkage value was needed tO be studied further． The strength of M—AAS Was comparatively high．but the flexural strength Was regressed in the long term．The compressive and flexural strengthes of 3 days were able to surpass 8MPa and 78MPa，respectively,and compressive strength of 90 days were all around 100MPa，but compared tO flexural strength of 28 days，the flexural strength of 90 days Was regressed by 1 9．O％．The high strength property of M—AAS associated with its hydration products and Interfacial Transition Zoo(ITZ)．The main hydration products of M—AAS were microcline and CSH．no calcium hydroxide Was found．The coexistence of microcline and CSH worked as micro—aggregate by each other,and weak ITZ，both resulted in its high strength，The regression of its strength Was related to its high shrinkage property,because the crazing caused by shrinkage woul