尖晶石型NTC热敏陶瓷材料性能研究-材料学专业论文.docxVIP

ABSTRACT ABSTRACT Negative temperature coefficient (NTC) thermistor is usually composed of two or more two or more than two transition metal oxide of Mn, Cu, Co, Fe, Ni, Zn etc., which are in a certain mixing ratio and produced through ceramic fabrication processes.NTC thermal ceramic material of spinel structure, generally can be expressed as AB2O4,and its resistivity and material constant vary with the change of material composition、sintering atmosphere、 sintering temperature and structural condition. At present, Mn-based NTC thermal ceramic materials are widely used in various industrial and domestic areas,as elements for the suppression of in-rush current, for temperature measurements and control, and for compensation for other circuit elements. In this paper,it’s mainly studied of NTC thermal ceramic materials of the Mn-Cu-X and Mn-X-Zn system.For the thermal ceramic materials of low-resistance-Mn-Cu-X system ,it’s mainly studied of the influence of the different metal oxides added on it’s R-T characteristics and material constant..For the thermal ceramic materials of high-resistance-Mn-X-Zn system ,it’s mainly studied of the influence of the factors in the process of material preparation 、 material composition and add other elements on it’s R-T characteristics and material constant. Keywords: NTC thermistor spinel structure electronic hopping model Mn-Cu-X Mn-X-Zn 目录I 目 录 I 目 录 第一章 绪论 1 HYPERLINK \l _TOC_250007 1.1 NTC 的发展历史及现状 1 NTC 的发展历史 1 NTC 的发展现状 2 HYPERLINK \l _TOC_250006 1.2 NTCR 的分类及应用 3 NTCR 的分类 3 NTCR 的应用 4 1.3 本文研究内容及结构 6 HYPERLINK \l _TOC_250005 第二章 尖晶石型 NTCR 的基本理论及性能参数 7 HYPERLINK \l _TOC_250004 2.1 尖晶石型 NTCR 的晶体结构 7 2.1.1 尖晶石结构 7 2.1.2 阳离子分布规律 8 HYPERLINK \l _TOC_250003 2.2 尖晶石型 NTCR 的导电机理 8 2.2.1 导电机理的建立 9 2.2.2 跳跃导电模型 9 HYPERLINK \l _TOC_250002 2.3 NTCR 中金属离子性质及性能调控 10 2.3.1 NTC 陶瓷材料中不同金属离子的作用 10 2.3.2 NTC 陶瓷材料中载流子浓度的调控 11 HYPERLINK \l _TOC_250001 2.4 NTCR 的性能参数 11 HYPERLINK \l _TOC_250000 第三章 NTCR 的制备工艺及测试 15 3