建筑磷石膏改性分析与应用-材料科学与工程专业论文.docx

重庆大学硕士学位论文 重庆大学硕士学位论文 1 1 绪 论 IV IV PAGE PAGE 13 exploit the produce of paint, adhesive and putty material of phosphogypsum-based on improving research . The results showed that: the addition of retarder reduces liquid supersaturation of phosphogypsum on the best pH value, leading to crystal grains become larger, the less of touchpoint of crystal, the net-structureing of crystal become loose and resulting in decreased strength;1220 redispersible powder and modified polycarboxylic ether of water-reducing can improve the strength of hardening;hydroxypropyl methyl cellulose of 100 000 viscosity can significantly improve water-keeping properties of the plaster of phosphogypsum;mixing with silicone waterproofing agent can greatly improved water resistance; phosphogypsum-based mortar will possess excellent features if mixed with citric acid. Analysis,utilization of retarder is a key factor which affects the dissolution of gypsum crystals, nucleation and growth process under the same conditions of grade of phosphogypsum, impacting the properties of phosphogypsum-based materials on natural dimensions as well. Water-reducer and dispersible polymer powders play the roles of compacting and reducing the porosity of hardened. Dispersible polymer powders can also improve paint, adhesive and putty materials of the phosphogypsum-based on the adhesive properties of phosphogypsum as well as plays an important role in the improvement, while the remaining additive effects only play a supporting modification. Keywords: Phosphogypsum, pH Value, Admixture, Hydrated Process, Modification Phosphogypsum-based MaterialsModification 1 绪 论 1.1 磷石膏利用的紧迫性及粉体材料的应用概况 1.1.1 发展建筑磷石膏基建材的现实意义及前景 随着磷酸、磷肥和洗涤剂等化学工业的发展，以硫酸钙为主要成分的工业废 渣也在急剧地增长。2007 年我国湿法磷酸总产量超过 1150 万吨 P2O5[1 , 2]，生产过 程中副产磷石膏年排放总量已近 5000 万吨（干量计），全球磷石膏年排放量也超 过 2.8 亿吨[3 , 4]，其堆放处理的环保和场地压力十分突出。其中，中化重庆涪陵化 工有限公司磷石膏年排放量已达到 200 万吨，磷石膏的资源化利用急需深入开展， 本文针对该公司的磷石膏性能改善展开研究并实现其资源化利用。 磷石膏的处理和利用方法很多[5 ~ 9]，在没有选择到一种技术、经济都合适的方 法以前，大多直接丢弃，或排入河、海中，或筑坝堆置