接枝改性氟硅原油破乳剂的合成及性能研究-化学工程与技术专业论文.docxVIP

和CMC先减小后升高，其中PEFB3的CMC和YCMC分别低至0．373 和CMC先减小后升高，其中PEFB3的CMC和YCMC分别低至0．373 g／L和 21．40 mN／m，PEFH3的CMC和代MC分别低至21．26 mN／m和0．355班； 聚合物PEFB及PEFH溶液的r先增大后减小，A与之相反，CAC的变化 趋势与CMC类似。经氟改性后聚合物具有更高的表面活性。 最后采用瓶试法探究了上述表面活性剂对河庄坪和定边原油乳状液破 乳效果的影响，并对复配后破乳剂浓度、温度、pH值和矿化度的破乳性能 进行评价。结果表明：上述制备聚合物对原油均有一定的破乳效果，其中 PEFB3破乳剂对两种原油破乳率可达62％和56％。复配后原油乳状液破乳 率大幅提高，当PEFB2：L61=2：1时，河庄坪原油破乳率可达85％，定边原 油破乳率达83％；三元复配破乳剂PEFB2-L61-M(PEFB2：L61：M--4：2：1) 对两种原油破乳率高达98％和95％。另外对破乳剂PEFB2．L61句订进行性 能评价，发现破乳剂PEFB2．L61．M对两种原油均具有良好的破乳性和一定 的耐酸碱、耐盐性，适用范围较广。 关键词：接枝，氟硅表面活性剂，临界胶束浓度，表面张力，破乳性 Ⅱ 万方数据 STUDY STUDY oN PREPARATIoN AND PRoPERTIES OF GRAFTED MoDIFIED FLUORINE SILICoN CRUDE oIL DEMULSIFIER ABSTRACT As the development of science and technology，crude oil play aJl increasingly important role in the politic and economy．So many measures have been taken to improve the oil recovery．Thus the oil become more and more stable，which brings great difficulties to demulsification．At present,many people are devoted to studing the polyether modified silicone oil emulsion breaking．However,few scholars have studied the long chain aH!(yl acrylate and fluorinated monomer into polyether modified silicone oil，moreover studied its solution properties and performance．This thesis based on the difficulty of crude oil demulsificatiort,preparing a clean and efficient system for a variety of crude oil demulsifier． Two amphiphilic grafted nonionic surfactants(PEH，PES)were synthesized， which used polyether as hydrophilic monomer,hydrogen silicone(PHMS)and long chain alkyl(acrylic sixteen ester and acrylic eighteen ester)as hydrophobic monome in the temperature of 95。C and reaction time of 7 h．The structure of polymers Was characterized via infrared spectroscopy(FT-rR)and nuclear magnetic resonance hydrogen spectrum(1H-NMR)；the micelle size and distribution in solution were discussed；the effect of hydrophobic content on the surfactant minimum surface tension(TcMc)and critical micelle concentration (CMC)Was analysised；the adsorption behav