金纳米粒子的形貌控制、自组装及SERS分析-冶金物理化学专业论文.docxVIP

西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 Morphology Control, Self-assembly and Surface Enhance Raman Scattering of Gold Nanoparticles Major: Physical Chemistry of Metallurgy Name: You Qi Instructor: Professor Zhao Junxue Professor Jiang Peng ABSTRACT It is of great value to expand the application of gold nanoparticles in biology, sensing and medicines by controlling the morphology and monodispersity. Therefore, the study reported a seed-mediate synthesis of decahedron gold nanoparticles with Poly (vinyl pyrrolidone) (PVP) act as a capping agent and Dimethyl Formamide (DMF) as a reducing agent. Also, truncated decahedron, five-pointed star decahedron, pentagon decahedron (PD) can be synthesized by decreasing the concentration of gold precursor (HAuCl4). In the twin crystal system, the synthesis achieved the transitions from decahedron to PD which composed of low energy {111} facets and high energy {110} facets respectively. At the same time, the octahedron gold nanoparticles have been synthesized by a seed-mediate method, truncated octahedron Ⅰ ,truncated octahedronⅡ,rhombic dodecahedron (RD) can be synthesized via decreasing the concentration of the seed4. The synthesis method can guarantee the morphology evolution of single crystal from octahedron to RD, which surrounded by low energy {111} facets and high energy {110} facets respectively. In general, to realize the conversion from low energy {111} facets to high energy {110} facets either in twin crystal or single crystal system, it is of great importance to control the twinned and single nanocrystal seed in the initial nucleation process of PVP+DMF system. In addition, the research investigated the optimal synthesis condition and growth mechanism of icosahedron twin gold nanoparticles that consist of twenty {111} facets with PVP and DMF by one-step synthesis without seed nanocrystal. To detect the effect of DMF served as a reducing agent, the 500nm RD gold nanoparticles were pr