金属氧化物纳米材料的制备及光催化性能研究-材料学专业论文.docxVIP

重庆理 重庆理工大学硕士学位论文 万方数据 万方数据 （4）最后尝试对二氧化钛与氧化锌纳米材料进行了贵金属 Ag 纳米颗粒的 负载，通过光化学还原法将 Ag 纳米颗粒负载到上述两种金属氧化物表面，对 样品结构的表征结果显示贵金属 Ag 纳米颗粒成功地负载到了金属氧化物纳米 材料表面，且光化学还原法负载并没有破坏原产物的微观结构。 关键词：自然纤维素；金属氧化物纳米材料；溶胶-凝胶法；光催化降解 II Abstract Abstract In this paper, metal oxide gel layer (TiO2 and ZnO and ZrO2) was deposited on the surface of nanofibers in cellulose material by natural cellulose substance (filter paper) as the template through the surface sol-gel method. After calcination to remove the filter templates and other organic residuum, functional metal oxide nanomaterials were obtained. These metal oxide nanomaterials faithfully inherits the hierarchical morphology and the complex network structure of the original ?lter paper template.Subsequently, the photocatalytic performance research on above three metal oxides nanomaterials have been studied. Finally, we have attempted to load precious metal silver nanoparticles on the surface of titanium dioxide and zinc oxide nanomaterials. The specific research results are as follows: Porous titania nanotubes are prepared through sol-gel methods by using natural cellulose substance ?lter paper and triblock copolymer Pluronic P123 micelles as dual templates. Characterization results show that the obtained product is pure anatase phase and its microstructure faithfully inherits the hierarchical morphology and the complex network structure of the original ?lter paper template. Each individual titania micro?bre is composed of many fine nanotubes and lots of mesopores are randomly distributed in the tube wall. The UV-Vis characterization indicates that the product exihibits very strong light absorption ability in the UV range. The photocatalytic activity for methyl orange dye degradation was tested under UV irradiation, the result shows that the sample displays significantly high photocatalytic activity. The dye was degraded by up to 50% in 8 minutes, and almost degraded completely at the time of 20 minutes. Porous zinc oxide nanosheets are prepared