羧甲基壳聚糖亚铁配合物的表征及其对CO的吸附-高校化学工程学报.PDF

第 25 卷第 1 期 高 校 化 学 工 程 学 报 No.1 Vol.25 2011 年 2 月 Journal of Chemical Engineering of Chinese Universities Feb. 2011 文章编号：1003-9015(2011)01-0091-05 羧甲基壳聚糖亚铁配合物的表征及其对 CO 的吸附研究 张新娜, 孙君社, 王淑豪, 张京声, 苗翠玲 ( 中国农业大学 食品科学与营养工程学院, 北京 100083) 摘 要：利用羧甲基壳聚糖吸附亚铁离子得到亚铁配合物，红外光谱显示羧甲基壳聚糖与 Fe2+发生了化学反应，同时 利用扫描电镜和差热分析对配合物进行表征，发现反应前后两者的微观结构和热性质发生了显著变化。将亚铁配合物 用于吸附 CO，结果表明，在反应时间为 6 h，温度为 40 ℃左右，颗粒度为 80 目时吸附量最高，可达1.75 mg⋅g− 1 。对 比发现，羧甲基壳聚糖亚铁配合物较羧甲基壳聚糖吸附 CO 效果提高 4 倍以上，且羧甲基壳聚糖亚铁配合物对 CO 的 吸附量高于壳聚糖亚铁配合物。 关键词：羧甲基壳聚糖；羧甲基壳聚糖亚铁配合物；CO ；吸附 中图分类号：Q599 文献标识码：A 2+ Study on the N-O-Carboxymethyl Chitosan- Fe Complex and its Adsorption of CO ZHANG Xin-na, SUN Jun-she, WANG Shu-hao, ZHANG Jing-sheng, MIAO Cui-ling (College of Food Science Nutritional Engineering, China Agricultural University, Beijing 100083, China) Abstract: N-O-carboxymethyl chitosan was used to adsorb Fe2+, which was indicated by FTIR. And the 2+ Fe -complex was characterized by SEM and DTA. Results show that the microstructure and thermal stability of the complex is significantly different from that of N-O-carboxymethyl chitosan. The Fe2+-complex was used to adsorb CO, and its adsorption capacity reached the maximum of 1.75 mg⋅g− 1 when the reaction was occurred at 40 ℃ for 6h and the granularity of the complex is 80 mash. The adsorbing capacity for CO of Fe2+-complex is up to 4 times higher than that of chitosan and N,O-CMC, and the adsorbing capacity of CMC-Fe2+ is higher than that of CTS-Fe2+ . Key words: N-O-carboxymethyl