Pd修饰Ti电极对水相中2,4,5-PCB还原脱氯的研究.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) 306 A cta Phys. Chim. Sin., 2006, 22(3) ：306 311 March [Article] Pd 修饰Ti 电极对水相中2,4,5 PCB 还原脱氯的研究 * 波 余 刚 黄 俊 (清华大学环境科学与工程系, 北京 100084) 摘要 实验研究了Pd 修饰Ti 电极对甲醇/水相中十六烷基三甲基溴化铵(CTAB)增溶的2,4,5鄄PCB(PCB ：多氯联 苯)的电化学还原脱氯作用. 采用两室流通式电解池, 考察了Pd 负载量、电极结构、电场条件和溶液流速对2,4,5鄄 PCB 的去除效率的影响. 优化条件是：Pd 负载量为3 mg ·cm-2, 阴极为3 层电极极板, 电极电位为-1.10 V(vs SCE) ；溶液流速对脱氯效率的影响不明显. 在该条件下经 9 h 电解, 2,4,5鄄PCB 的去除率达96.2%, 脱氯产 未 完全生成联苯, 其产率为89.6%, 电流效率介于11.3%~33.0%之间. 关键词： Pd 修饰Ti 电极, 多氯联苯(PCBs), 电催化, 还原脱氯 中图分类号： O646 Electrocatalytic Reductive Dechlorination of 2,4,5 PCB in Aqueous Solution by Palladium modified Titanium Mesh as Cathode YANG, Bo YU, Gang* HUANG, Jun (Department of Environmental Science and Engineering, Tsinghua University, Beiji ng 100084, P. R. China) Abstract Electrocatalytic reductive dechlorination of 2 ,4 ,5 鄄PCB (PCB ：polychlorinated biphenyls) in aqueous solution containing methanol and hexadecyltrimethyl ammonium bromide (CTAB) was studied in a Teflon鄄made two鄄 compartment flow鄄through cell with a palladium鄄loaded permeable titanium mini mesh cathode and a platinum foil anode. The experiments were carried out to explore the effects of palladium loading, electrode structure, applied cathode potential and catholyte flow rate on dechlorination. The results indicated that the optimal conditions were 3 mg 2 Pd