超分子结构化学.pptVIP

第七章 次级键及超分子结构化学 Hydrogen bonds Hydrogen bonds are also weak forces of attraction. It is an attraction between a Hydrogen atom and a strong electronegative atom such as O, F, or N. These bonds are important in biological and chemical systems. For example, hydrogen bonds account for many of the unusual propertied of water such as high boiling point and high dielectric constant (介电常数， 电容率 ). Intermolecular and intramolecular hydrogen bonds can occur. Hydrogen bonds are relatively weak a in few numbers but are very strong in large numbers. 氢键的影响 熔点、沸点、熔化热 、气化热、蒸汽压、溶解度、粘度、表面张力、密度、酸碱性、介电常数、红外光谱振动频率