急冷条件下Cu-Sn合金的快速枝晶生长-中国有色金属学报.PDF

第 17 卷第 9 期 中国有色金属学报 2007 年 9 月 Vol.17 No.9 The Chinese Journal of Nonferrous Metals Sep. 2007 文章编号：1004-0609(2007)09-1521-06 急冷条件下 Cu-Sn 合金的快速枝晶生长 杨 扬，徐锦锋，翟秋亚 (西安理工大学 材料科学与工程学院，西安 710048) 摘 要：研究快速凝固 Cu-x Sn(x=7%, 13.5%, 质量分数)合金的相结构、组织形态和枝晶生长特性，将金属熔体热 传导方程与 Navier-Stokes 方程相耦合，从理论上计算液态合金的冷却速率。结果表明：在急冷快速凝固条件下， Cu-7%Sn 合金形成过饱和的单相α-Cu 固溶体组织；Cu-13.5%Sn 合金形成以亚稳的 Cu13.7Sn 相为主相、α-Cu 为第 二相的快速凝固组织；随着冷却速率的增大，溶质截留效应增强，合金相结构由复相向单相转变；沿垂直于辊面 方向上合金的组织形态依次为近辊面细小等轴晶、中部柱状晶及自由面粗大等轴晶；增大冷却速率，晶体形态由 柱状晶向等轴晶转变；在急冷快速凝固过程中，α-Cu 和 Cu13.7Sn 相均以枝晶方式生长；随温度梯度的增大，晶体 生长速率呈线性增大。 关键词：Cu-Sn 合金；单辊法；急冷快速凝固；晶体生长 中图分类号：TG 164.1; TG 113.12 文献标识码：A Rapid dendritic growth in melt-spun Cu-Sn alloys YANG Yang, XU Jin-feng, ZHAI Qiu-ya (School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China) Abstract: The phase structure and microstructural characteristics of rapidly solidified Cu-x Sn(x=7%, 13.5%, mass fraction) alloys were investigated. The cooling rate was calculated theoretically by coupling the heat conduct equation and Navier-Stokes equation. The results show that under rapid solidification condition, the single phase α-Cu solid solution is formed in Cu-7%Sn alloy. The microstructure of Cu-13.5%Sn alloy consists of main phase Cu13.7Sn and a few of α-Cu phase. With increasing cooling rate, the effect of solute trapping is enhanced, and the phase structure changes from multiphase to single-phase. The microstructures of the alloy along the direction vertical to wheel surface are charac