光解水催化剂介绍photocatalysts.ppt

赵宇 黄子健 王宏宇 2016年11月23日 Photo-catalysts for water splitting contents 1、Basic principles and developing history 2、Strategies to improve the photocatalytic activity 3、The outlooks of the photocatalytic materials first discovery and basic principles First discovered at 1972 initiated by the demonstration of photo-electrochemical (PEC) well-known as the Honda-Fujishima effect first discovery and basic principles energy band theory full-occupied half-occupied unoccupied band gap CB VB different energy levels correspond with different bands semi-conductors are very useful in this area K. Maeda / Journal of Photochemistry and Photobiology C: Photochemistry Reviews 12 (2011) 237–268 first discovery and basic principles Half-reactions using sacrificial electron donors and acceptors test reactions for overall water splitting first discovery and basic principles specific needs that must be met 1、the band gap restriction 2、migrate without recombination 3、inhibit the backward reaction K. Maeda / Journal of Photochemistry and Photobiology C: Photochemistry Reviews 12 (2011) 237–268 generally to be particles example: Pt-TiO2 at 1980 with NaOH loaded on the cocatalyst first discovery and basic principles major developing history special structures—the well-known lamellar particle major developing history special structures—perovskites Cubic Perovskites Double Perovskites major developing history Aurivillius phases Dion-Jacobson phases Ruddleson-Popper phases special structures—perovskites major developing history amazing effects of the network of octahedral units of metal cations probably from its unique electronic properties special structures—perovskites major developing history special structures：Ruddlesden–Popper type layered perovskites of A2La2Ti3O10 [32] T.Takata,K.Shinohara,A.Tanaka,M.Hara,J.N.Kondo,K.Domen,J.Photochem. Photobiol. A: Chem. 106 (1997) 45. a series of layered perovskites have AQYs higher than 20% under UV irradiation