Al2O3上谷氨酸吸附和热缩合反应的漫反射红外光谱研究.docxVIP

A1203上谷氨酸吸附和热縮合反应的漫反射红外光谱研究 郭丽红，孟明，查宇清 (天津大学化工学院催化科学与工程系，天津300072) 摘要：采用TG-DTA. XRD和DRIFT等手段对谷氨酸在AI2O3表面的吸附和热缩合反应 进行了研究。结果表明，谷氨酸在AI2O3表面的吸附位主要是AI2O3表面的Lewis酸位,低 浓度时符合Langmuir单层吸附模型；高浓度时为多层吸附，谷氨酸分子之间通过氢键重构 形成新的晶相；吸附的谷氨酸分子和载体之间形成二齿鳌合物，200°C左右首先分子内脱水 生成焦谷氨酸。 关键词：谷氨酸氧化铝吸附热缩合焦谷氨酸 中图分类号：TQ116.2 文献标识码：A A DRIFT Study on the Adsorption and ThermalCondensation of Glutamic acid on A12O3 GUO Lihong, MENG Ming *, ZHA Yuqing (Department of Catalysis Science and Technology, School of Chemical Engineering, TianjinUniversity, Tianjin 300072) Abstract： L-a-glutamic acid was adsorbed on the surface of alumina from aqueous solution with variable concentrations and pH values? The adsorption and thermal condensation performances of glutamic acid on alumina were investigated by TG/DTA, XRD and DRIFT techniques? The results of the adsoiption experiment indicate that the adsorption performance was prominently influenced by the equilibrium concentration and pH value of glutamic acid solution. When the initial concentration is below 0.4 mol/L, the adsorption isotherm meets Langmuir model. The adsorbed glutamic acid molecule is bidentately binding to the Lewis-acid site on alumina surface through a-carboxyl group; at higher concentration (0.4mol/L), the multi-layer adsorption phenomena are observed, which leads to the precipitation and crystallization of p-glutamic acid on alumina surface? The lower pH value, the larger adsoiption amounts. At about 200°C, the cyclic anhydride bond is formed via the intra-molecular condensation reaction, and the main product is pyroglutamic acid, which bidentately binds to the surface of AI2O3 to form aluminium pyroglutamate species, which show high thermal stability. Key words: glutamic acid, alumina, adsorption, thermal condensation, pyroglutamic acid 联系人：孟 明?第一作者：郭丽红(1982—),女，博士研究生? Corresponding author： Prof. MENG Ming, E-mail: HYPERLINK mailto:mengm@tju.edu.cn mengm@tju.edu.cn 引言 有关地壳中含量丰富的SiO2、AI2O3及粘土等无机氧化物在早期生命进化过程中的作用 （如肽键和多肽的形成），曾引起许多研究者的关注2】。近年来，