一种水中可溶性导电聚苯胺的制备与表征Preparationand.PDF

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第21 期, 2210～2214 ACTA CHIMICA SINICA No. 21, 2210～2214 ·研究论文· 一种水中可溶性导电聚苯胺的制备与表征 原 玲a,b 隋春红a 尹 荣a 龚 剑*,a 瞿伦玉a (a 东北师范大学多酸科学教育部重点实验室 长春 130024) (b 内蒙古兴安职业技术学院化学系 乌兰浩特 137400) 摘要 分别以聚乙二醇(PEG)的水、乙醇溶液为反应媒介, 制备了Keggin 结构杂多酸(H4SiW12O40)掺杂的导电聚苯胺材 料. 此聚苯胺经IR, XRD, UV-Vis 光谱进行了表征, 并采用标准的四探针法对其电导率进行了测定. 同时系统地研究了 杂多酸、氧化剂和单体的比例、反应混合体系温度的改变等对所合成聚苯胺的产率、导电率、水中溶解性等方面的影 响. 结果表明, 在 PEG 乙醇溶液中制备的聚苯胺比在水溶液中制备的有较高的产率、电导率和溶解率. 其最高电导率 可达到1.87 S/cm, 溶解率可达53%. 关键词 聚苯胺; 掺杂; 电导率; 溶解率 Preparation and Characterization of A Soluble Conducting Polyaniline YUAN, Linga,b SUI, Chun-Honga YIN, Ronga GONG, Jian*,a QU, Lun-Yua a ( Key Laboratory of Polyoxometalates Science of Ministry of Education, Northeast Normal University, Changchun 130024) (b Department of Chemistry, Xingan Occupation Technic College , Wulanhaote 137400) Abstract Conducting polyaniline (PANI) doped with H SiW O was obtained in the polyglycol (PEG) 4 12 40 aqueous solution and PEG ethanol solution, respectively. The PANI was characterized by IR, XRD patterns and UV-Vis spectra. The conductivity of the PANI was measured by the four-probe method. The effect of the ratio of heteropoly acid (HPA), oxidant and aniline, and the temperature of the reaction system on the fi- nal yield, conductivity, and solubility of the PANI was investigated, respectively. The results showed that the performance of PANI synthesized in ethanol was better than