新型纳米结构二氧化锰的制备及其超级电容性能-河北科技大学学报.PDF

32 2 Vol. 32, No . 2 20 11 4 Journal of Hebei University of Science and T echnolo y Apr . 20 11 : 2011) 段立谦, 李景印, 李玉佩, 何前国 ( 河北科技大学理学院, 河北石家庄 050018) : 以M nSO4 和( NH4 ) 2 S2 O8 为主要原料, Fe( NO3 ) 3 为添加剂, 采用水热法制备了菜花 MnO2 运用XRD, SEM 对制备的M nO2 进行了形貌和结构分析通过循环伏安恒流充放电测 试和交流阻抗研究了M nO2 的电化学性能结果表明, 实验制备的M nO2 为型菜花 结构, 其在 6 mol/ L 的KOH 电解液中及0~ 0. 4 V 的电位范围内表现出良好的超级电容性能, 电流密度为 100 mA/ 时, 其比容量达到176 F/ : 水热法; M nO2 ; 超级电容器; 比容量 : T Q 137; TM 533 : A Preparation and supercapacitive performance of a novel nanostructural M nO2 DU AN Liqian, LI Jin y in, LI Yupei, HE Qian uo ( Colle e of Sciences, Hebei University of Science and T echnolo y, Shijiazhuan Hebei 0500 18, China) Cauliflower MnO was prepared by hy drothermal synthesis method by react in MnSO and ( NH ) S O w ith Abstract: 2 4 4 2 2 8 Fe( NO ) . The samples were analyzed by Xray diff raction( XRD) and scannin electron microscopy ( SEM ) . Cyclic voltam 3 3 metry and alvanostatic char edischar e w ere used to characterize the electrochemical performance of the samples. The results show that the prepared samples are MnO . The particles are in a cauliflower shape. In an electrolyt e of 6 mol/ L KOH , elec 2 t rode based on the MnO show perfect supercapacitor characterizat ion in the potent ial re ion of 0~ 0. 4 V . At a current density 2 of 100 mA/ , a specific capacitance of 176 F/ is achieved. hy drothermal synthesis; MnO ; s