无铁渣湿法炼锌提铟工艺-中国科技论文在线.PDFVIP

有色金属(冶炼部分) 2004年6期 ·27 · 无铁渣湿法炼锌提铟工艺 唐谟堂 ，李仕庆 一，杨声海 ，唐朝波 ，何静 ，彭长宏 ，姚维义 (1．中南大学冶金学院，长沙 410083；2．柳州华锡集团有限责任公司，柳州 545006) 摘要：提出了一种锌、铟清洁生产工艺，该方法在保留传统湿法炼锌主体流程的前提下，利用铁闪锌矿精 矿的铁资源、部分锌源及锰矿的锰源，直接制备高档次的锰锌软磁铁氧体材料。工艺过程包括：中浸渣 高温高酸浸出、还原及除铜、萃取提铟、初步净化、深度净化及开路锌、共沉淀、铁氧体制备等。本方法取 消了湿法炼锌流程中的除铁过程，作到铁渣和SO 的零排放，简化了湿法炼锌提铟流程，大幅度提高铟 锌回收率；同时解决了“直接共沉淀法”铁源的长期供应问题。 关键词：铟；湿法炼锌；无铁渣；软磁材料 中图分类号：TF813。TF843．1 文献标识码：A 文章编号：1007—7545(2004)06—0027—04 The Hydrometallurgy of Zinc and Indium without Iron Residue TANG Mo—tang ，LI Shi—qing 一，YPuNG Shen—hai ，TANG Chao—bo ，HE Jing 。 PEN Chang—hong ，YAO Wei—yi (I．School of Metallurgical Science and Engineering．Central South University．Changsha 410083，China： 2．Liuzhou Huaxi Group Corporation．Liuzhou 545006，China) Abstract：A clear zinc hydrometallurgical process is proposed．By using iron and part of zinc in sphalerite concen— trates and manganese in pyrolusite，high quality Mn—Zn soft magnetic ferrites can be directly prepared in the process，going on premise remaining the neutral leaching，purification and electrowinning in the traditional zinc hydrometallurgy flow sheet．This method includes the following processes，such as leaching the neutral leached residue with high concentration sulphuric acid at high temperature，reduction and copper removing，indium ex— tracting，the primary purifying，deeply purifying and zinc separating，coprecipitating and preparing Mn—Zn soft magnetic ferrites，etc．This process cancel the iron removing process in traditional zinc hydrometallurgy flow sheet，SO it has the following advantages：no discharging of iron residue and SO2，simplify the indium recovering process，increasing the indi