单一及复合淋洗剂淋洗修复污染土壤实验探究.pdfVIP

第46卷第1期 应　 用　 化　 工 Vol.46 No.1 2017年1月 Applied Chemical Industry Jan.2017 单一及复合淋洗剂淋洗修复污染土壤实验研究 许端平,谷长建,李晓波,李晓东 (辽宁工程技术大学 环境科学与工程学院,辽宁阜新　 123000) 摘　 要:以辽宁省某锌厂附近农田耕作层(0~20 cm)土壤为研究对象,分别以柠檬酸(CA)、柠檬酸-十二烷基苯磺 酸钠复合剂(CA-SDBS)作为淋洗剂,采用振荡淋洗法研究在不同实验条件下两种淋洗剂对Pb 的去除效果及动力 学特征。 结果表明,随液固比增大、淋洗剂浓度增大、pH降低和温度升高,两种淋洗剂对Pb 的去除率均增大,且在 各个条件下CA均比CA-SDBS的淋洗效果好,说明CA与SDBS 的复合表现出拮抗作用;CA和SDBS-CA淋洗修复 污染土壤中Pb时,最佳的环境条件为水土比20∶1 mL/ g,淋洗剂浓度0.2 mol/ L,温度45 ℃,pH=3,此时CA、CA- SDBS的Pb去除率分别为55%,27%;该淋洗过程符合准二级动力学。 关键词:污染土壤;淋洗修复;十二烷基苯磺酸钠;柠檬酸;Pb 中图分类号:TQ028.1-5;X53　 　 文献标识码:A　 　 文章编号:1671-3206(2017)01-0037-04 Study on leaching of heavy metal-contaminated soil with organic acids XUDuan-ping,GUChang-jian,LI Xiao-bo,LI Xiao-dong (College of Environmental Science and Engineering,Liaoning Engineering Technology University,Fuxin 123000,China) Abstract:Soil samplescollectedfromHuludaoCity,LiaoningProvince,wherethecropsnearazincplant, compositing agent as leaching agent,by the use of citric acid,citric acid and SDBS,through the batch of testing researches on two kinds of eluent agents’removal effectsto solid liquid ratio,leaching agent con- centration,pH and temperature effect within the desorption kinetic characteristics.The results show that the leaching effect of twokindsof eluent agentswhichthecompositeisrelativelyweakaswell asshowing that those two kinds of agent reflects the existence of antagonism between them,and the single citric acid leaching effectisbetter,upontheheavymetalleadcitricacidleachinginsoil;CAandSDBS-CAremedia- tion of contaminated soil Pb,the optimal environmental conditionsfor soil andwater ratio of20∶1mL/ g, the concentrationof0.2 mol/ L,45 ℃,pH=3,atthistimeofPbr