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47 1 Vol.47 No.1
2018 1 Applied Chemical Industry Jan.2018
,
( , 750021)
:2--4-(GO-IPDI-EMI)。 Friedman
,GO-IPDI-EMI ,Tp Tonset
。 Kamal k k ,
2 1
Ea2 Ea1 ,。
,。
:;;;;;
:TQ 323.5 :A :1671 -3206(2018)01 -0066 -04
Preparation and curing kinetics of dicyandiamide
flame retardant epoxy resin
LI U Lin-lin ,YANG Tian-lin
(College of Chemistry and Chemical Engineering ,Ningxia University,Yinchuan 750021,China)
Abstract :2-Ethyl-4-methylimidazole modified graphene oxide (GO-IPDI-EMI) was used to cure the di-
cyandiamide flame retardant epoxy resin .Friedman method was used to detect the effect of GO-IPDI-EMI.
The peak activation temperature Tp value and the starting temperature Tonset value of the non-isothermal
heat flow map decrease with the increase of the modified graphene content after modification .The isoki-
netic cure rate constants k and k were calculated by Kamal model ,and the corresponding autocatalytic
2 1
activation energy E and non-catalytic activation energy E were obtained by using k and k ,the modi-
a2 a1 2 1
fied cyanide Amine epoxy flame retardant system activation energy decreased significantly .Finally,the
rheological and calorimetric analysis showed that the modified graphene oxide had a good catalytic effect
on the curing of dicyandiamide flame retardant epoxy resin .
Key words :flame retardant epoxy resin;dicyandiamide;catalytic;calorimetric method;rheology;hardener
,E51 ,NLV
[1] 。
,。 2--4-
(EMI-2 ,4 )、
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