光皮树油催化异构化反应产物结构分析-生物质化学工程.PDF

第43卷第2期 生摇 物摇 质摇 化摇 学摇 工摇 程 Vol.43 No.2 2009年3月 Biomass Chemical Engineering Mar. 2009 光皮树油催化异构化反应产物结构分析 聂小安,夏建陵,常侠 (中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室; 国家林业局林产化学工程重点开放性实验室, 江苏 南京 210042) 摘摇 要:以光皮树油为原料,对不饱和脂肪酸于碘、三氯化钌及碱3种催化剂催化异构化反应进行了研究,探讨了孤立双 键与共轭双键转化机理,通过UV、GC、GC-IR及GC-MS法,分析了共轭酸的主要成分、共轭结构及构型。 结果表明,异构 化催化剂对光皮树油共轭酸构型起决定性作用,氢氧化钠催化异构化共轭酸构型以顺-反式为主,而三氯化钌及碘催化 异构化共轭酸构型则同时生成顺-反式及反-反式,两种构型比例为1 颐1。 关键词:光皮树油;催化异构化;共轭化 中图分类号:TQ91;TQ517摇 摇 摇 摇 摇 摇 摇 文献标识码:A摇 摇 摇 摇 摇 摇 摇 文章编号:1673-5854(2009)02-0011-04 Structure鄄analysis of Isomerized Products of Comus wilsoniana Fruit Oil NIE Xiao鄄an,XIA Jian鄄ling,CHANG Xia (Institute of Chemical Industry of Forest Products,CAF;National Engineering Lab.for Biomass Chemical Utilization;Key and Open Lab.on Forest Chemical Engineering,SFA,Nanjing210042,China) Abstract:The isomerization of Comus wilsoniana fruit oil by the catalysts such as I ,RuCI and alkaline were studied. The 2 3 mechanism of isolated double bondstoconjugateddoublebondswasdiscussed. Theconstituentsof isomerizedproductswerealso analyzed by the methods of UV,GC,GC鄄IR,GC鄄MS.It has been found that the catalysts had the most important effect on the configuration ofisomerizedproducts.Theconjugatedconfigurationsbythealkalinecatalystwerecis鄄trans,andtheconjugatedcon鄄 figurationswere both cis鄄trans and trans鄄trans by I and RuCl ,meanwhile the proportion of both configurationswas 1 颐1. 2 3 Key words:Comus wilsoniana fruit oil;catalysis isomerization;conjugationion 摇 摇 光皮树油是由光皮树(Comus wilsoniana) 种 构化反应进行研究,对光皮树油催化异构化反应