复凝聚法制备石蜡相变储能微胶囊及其性能探究.pdfVIP

47 1 Vol.47 No.1 2018 1 Applied Chemical Industry Jan.2018 ，，，，， （ ， 450001） ：，，。 ， pH、、、。 、 、、。 ， （pH ＝4.5 ，20 min，1.5∶1，2 mL）20 ～30 μm ， 52.84％，56.27％。 ／，。 ：；；； ：TQ 316.64 ；TB 34 ：A ：1671 －3206（2018）01 －0010 －04 Preparation and properties of microencapsulated paraffin phase change material by complex coacervation HAI Bin ，JIANG Gao-liang ，L U Lei-ming ，LI U Li ，LI U Yong ，TANG Jian-wei （School of Chemical Engineering and Energy ，National Centre of Research ＆ Popularization on Calcium ，Magnesium， Phosphate and Compound Fertilizer Technology ，Zhengzhou University ，Zhengzhou 450001，China） Abstract ：The paraffin was microencapsulated with chitosan and gum arabic by a complex coacervation . The effect of pH，complex coacervation time ，core／shell mass ratio and the amount of crosslinking agent on encapsulation ratio and encapsulation efficiency were investigated by experiment of single factor .Scanning electronic microscope （SEM），fourier transformation infrared spectroscope （FTIR），differential scanning calorimeter（DSC） and thermogravimetric analyzer （TGA） were used to characterize the microstructure ， chemical structure and thermal properties of microcapsules .The diameter of microcapsules was 20 ～ 30 μm when the pH was 4.5 ，complex coacervation time was 20 min，core／shell mass ratio reached 1.5∶1 and the amount of crosslinking agent was 2 mL.The DSC results indicated that the encapsulation ratio of microcapsules was 52.84％ and the encapsulation efficiency was 56.27％.The shell could also protect the encapsulated paraffin and thermal stability of the microcapsule was improved . Key words ：paraffin； chitosan； gum arabic； microcapsule ，、 。 ［1