表面活性离子液体溴化N-十二烷基异喹啉与非离子-IngentaConnect.PDF

物理化学学报(Wuli Huaxue Xuebao) 356 Acta Phys. -Chim. Sin . 2016, 32 (1), 356–364 January [Article] doi: 10.3866/PKU.WHXB201512012 表面活性离子液体溴化N-十二烷基异喹啉与非离子表面活性剂 Triton X-100在水溶液中的混合胶束 张晓红 许红岩 葛玲玲 郭 荣* (扬州大学化学化工学院，江苏 扬州 225002) 摘要：用等温滴定微量热法测定表面活性离子液体溴化N-十二烷基异喹啉([C12iQuin]Br)与非离子表面活性剂 1 Triton X-100混合物在水溶液中的临界胶束浓度。并以 H核磁共振(NMR)和二维核Overhauser效应增强谱 (2D NOESY)研究[C12iQuin]Br与Triton X-100在混合胶束中的作用机理。研究结果显示：混合胶束中，Triton X-100分子的苯环定位于混合胶束的内核，聚氧乙烯链卷曲在异喹啉环周围。本文还应用规则溶液理论和浊 点法对比研究了十二烷基三甲基溴化铵(DTAB)-Triton X-100混合胶束体系的相关性质。 关键词：表面活性离子液体；溴化N-十二烷基异喹啉；Triton X-100 ；混合胶束；浊点 中图分类号：O648.1 Mixed Micelle of Surface Active Ionic Liquid Lauryl Isoquinolinium Bromide and Nonionic Surfactant Triton X-100 in Aqueous Solutions ZHANG Xiao-Hong XU Hong-Yan GE Ling-Ling GUO Rong* (School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, Jiangsu Province, P. R. China) Abstract: The critical micelle concentrations of binary systems of surface active ionic liquid lauryl isoquinolium bromide ([C12 iQuin]Br) with nonionic surfactant Triton X-100 in aqueous solution were investigated by isothermal titration calorimetry. The location of [C12iQuin]Br and Triton X-100 in the mixed 1 micelle was studied using H nuclear magnetic resonance (NMR) and