CaCO3SiO2复合粒子涂层的表面结构及其疏水性能研究.PDFVIP

24 1 Vo.l 24, No. 1 2009 1 Journal of InorganicMaterials Jan., 2009 : (2009) 0120091206 C aCO 3 / S iO2 杨金鑫, 文秀芳, 皮丕辉, 郑大锋, 程江, 杨卓如 ( , 510640) : CaCO /SiO , . 3 2 , / 0, 169b, 2b. , 2. 2~ 3Lm , 200nm , . , . : Cassie. , . : ; ; : O647 : A Stu dy on M orph ology an d H ydr op h ob ic ity of C aCO 3 / SiO 2 C om p osit e Su r face C oatin g YANG Jin2Xin, WEN Xiu2Fang, PI Pi2H ui, ZHENG Da2Feng, CHENG Jiang, YANG Zhuo2Ru (The School ofChem istry and chem icalEngineering, South ChinaU niversity ofTechnology, Guangzhou 510640, China) Ab str act: A superhydrophobic CaCO /SiO composite surface coating, with a very high water contact angle 3 2 (WCA) of 169b and a small sliding angle ( SA) of2b, was prepared bym eans of self2assemb ly function of polydmi ethylsilioxane ( PDMS). Dual2size surface roughness, which m mi icked the surface topology of the lo2 tus leaf, was originated from well2defined CaCO / SiO raspberry2like particleswhich were prepared by vio2 3 2 lent stirr ing and surfacemodification. The coating surfacemorphologieswere observed with scann ing electron m icroscope. Roughness andWCA were measuredwith atom forcem icroscope andWCA tester, respectively. It is found that there aremanym icroconvexitieswith b inary structure un iform ly distributed on the surface low2 er of the fiml with diameter ofabout 2 to 3Lm and nanoconvexities or subm icroconvexities on the atop surface layer of the coatingwith diam eter of about 200nm, and the surfacem icrostructure is smi