对氯苯甲酸用于测量OH#方法探讨2误差分析.pdf

第25 卷第 11期 环 境 科 学 学 报 Vol. 25,No. 11 2005 年11 月 Act Scienti e Circumst nti e Nov. , 2005 皮运正, 王建龙. 对氯苯甲酸用于测量OH# 方法探讨2. 误差分析 [J] . 环境科学学报, 2005,25( 11) : 1560- 1564 PI Yunzheng, WANG Ji nglong. Investig tion of p r 2chlorobenzoic cid used for the detection of OH# r dic ls 2. Error n lysis [ J] . Act Scienti e Circumst nti e,2005, 25( 11) : 1560- 1564 OH#2. * , 清华大学核能与新能源研究院环境技术研究室, 北京 100084 : 2005208230 :16 16 : 对氯苯甲酸用于测量臭氧氧化 程中产生的OH# 浓度时会产生误差. 为了研究误差的大小, 进行了臭氧的间歇实验, 以测量臭氧分解速 率常数 k. 通 对比乙二酸、甲苯和腐殖酸溶液中投加对氯苯甲酸前后k 值的变化, 判断投加的对氯苯甲酸是否能引起测量误差及误差大小. 试验结果表明, 含清除剂少的水样, 对氯苯甲酸测量OH# 浓度时会引起很大的误差. 在对氯苯甲酸捕获率小于 10% 的水样中, 对氯苯甲酸测量 OH# 时产生的误差小. 在捕获率大于20% 的水样中, 采用对氯苯甲酸测量OH# 会产生较大误差, 不能用来测量OH# 浓度. : 臭氧; 对氯苯甲酸; 误差分析; OH# ; 对氯苯甲酸捕获率 : 025322468(2005) 112 1560205 :X132 : A Investigation of para2chlorobenzoic acid used for the detection of OH# radicals 2. Error analysis * PI Yunzheng , WANG Ji nglong L bor tory of Environment l Technology, Institute ofNucle r nd New Energy Technology, Tsinghu University, Beijing 100084 Received 30 August 2005; received in revised form 16 September 2005; accepted 16 September 2005 Abstract: There re errors when pplying p r 2chlorobenzoic cid (pCBA) to me sure OH# r dic ls during ozon tion processes. To investig te the errors, b tch tests were c rried out to me sure the ozone dec y r te k. The v ri tion of k v lues of ox l te, toluene nd humic cid s mples with or without pCBA could tell whether the used pCBA le ded to detect ble error nd how big ofthe error. The results showed th t pCBA le ded to obvious errors when it w s usedto detect OH# r dic ls in low sc venger cont ining s mples. In s mples, when thepCBA sc venging r te w s less th n 10% , the error of using pCBA to det