重金属离子於焚化飞灰中的表面结构与扩散行为.DOC

重金屬離子於焚化飛灰中的表面結構與擴散行為 Studies on the Surface Structure and Diffusivity of Heavy Metal in Incineration Fly Ash 研究生: 李仲虔 Chung-Chien Lee 指導教授: 黃武章 Wu-Jang Huang [摘要] 目前有許多的分析方法已用來研究焚化灰中重金屬的擴散，其方法包括核磁共振光譜學（Nuclear Magnetic Resonance Spectroscopy）和紅外線吸收光譜學（Infrared Absorption Spectroscopy）。本研究利用紅外光譜儀器分析法與連續淋洗法以直接或間接的方式求得處理前與處理後飛灰內鉛金屬的擴散係數，以及了解重金屬離子於灰粒表面的鍵結方式。而在紅外線光譜法中，我們所使用的傅立葉紅外線調減全反射裝置（FTIR-ATR），它有以下優點包括對表面的感光度較高及直接測量分子層級的作用力及擾動現象。經由傅立葉紅外線光譜調減全反射裝置（FTIR-ATR）求得各廠飛灰表面化學成份為SiO2、CO32-、NOX。本實驗中應用Fick，s Law 數學式且代入適當的初始與邊界條件未求得焚化灰中擴散過程的擴散係數。在ATR-FTIR擴散係數測量，可求得各廠FA與RP之擴散係數，其D值介於10-7~10-8 cm2/s，增加水泥的添加量後，其D值介於10-8cm2/s左右，而由淋洗液連續淋滲後，未添加水泥之FA中鉛D值為7*10-9 ，添加水泥後D值為1.5*10-10 ，顯示利用紅外光譜儀器分析法與連續淋洗法中都可測得鉛離子的擴散係數。 關鍵字: 集塵灰、洗煙塔底灰、傅立業紅外線光譜調減全反射裝置、擴散係數 【Abstract】 Many techniques such as nuclear magnetic resonance spectroscopy（NMR） and infrared absorption spectroscopy are available for a determination of effective diffusivity of heavy metals in incineration fly ash. In this study we used total attenuation reflection fourier transform infrared infrared（ATR-FTIR） spectroscopic method and column leaching test were need to determine diffusion coefficients（D） of lead（II） and surface bonding types of treated and untreated incineration fly ash. The ATR-FTIR spectroscopy has been employed on measuring the diffusivity of small molecules, the advantages of the technigue are having high surface sensitivity and monitoring on molecular-level interactions and perturbations. Results from ATR-FTIR spectra of the untreated fly ash show that the NOX, CO3- 2 and SiO2 components are riching on the surface of fly ash. Fick’s law diffusion equation and experimtal initial and bounding conditions were applied to obtain the D values of Pb in the fly ash in this study. The D values obtained from ATR-FTIR are ranging from 10-7cm2/s to 10-8 cm2/s. After cement were mixing with fly ash, the D values are near to the order of 10-8 cm2/s. The D values obtained from column leaching closed to the order of 7×10-9 cm2/s. D a