液液萃取结合气-质联机分析景芝白干酒中的挥发性成分-食品科学.PDFVIP

72 2014, Vol.35, No.08 食品科学 ※分析检测 液液萃取结合气-质联机分析景芝白干酒中的 挥发性成分 * 吴继红，黄明泉 ，孙宝国，郑福平，孙金沅 （1.北京工商大学 北京市食品风味化学重点实验室，北京 100048 ； 2.北京工商大学 食品添加剂与配料北京高校工程研究中心，北京 100048 ） 摘 要：采用不同的溶剂，通过液液萃取法结合气-质联机对景芝白干酒中的香气成分进行分析，并通过NIST 11 谱库 检索和保留指数进行了鉴定。结果表明，不同种类和极性的有机溶剂，其萃取出来的成分也不相同。采用正戊烷作为 萃取剂，共发现30 种物质，采用乙醚作为萃取剂，共发现29 种物质，采用二氯甲烷作为萃取剂，共发现35 种物质。 3 种溶剂一共萃取出65 种物质，其中醇类化合物9 种、酯类化合物19 种、酸类化合物11 种、烃类化合物14 种、芳香 族化合物3 种、呋喃类化合物3 种、醛类化合物3 种、酮类化合物1 种、含氮化合物1 种、含硫化合物1 种。 关键词：液液萃取；有机溶剂；景芝白干酒；香气成分；气相色谱-质谱法 Analysis of Volatile Compounds in Jingzhi Baigan Liquor by Liquid-liquid Extraction (LLE) and Gas Chromatography-Mass Spectrometry (GC-MS) * WU Ji-hong, HUANG Ming-quan , SUN Bao-guo, ZHENG Fu-ping, SUN Jin-yuan (1. Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing 100048, China; 2. Beijing Higher Institution Engineering Research Center of Food Additives and Ingredients, Beijing Technology and Business University, Beijing 100048, China) Abstract: Volatile compounds of Jingzhi Baigan liquor were analyzed by liquid-liquid extraction and gas chromatography- mass spectrometry and identified by mass spectral library searching and comparison of retention indexes. Different compounds were extracted by using different kinds of organic solvents with various polarities. The results showed that 30 compounds were identified in n-pentane extract compared to 29 compounds in ethyl ether extract and 35 compounds in dichloromethane extract. In total, 65 compounds were extracted with three organic solvents in