三腈基呋喃推拉型电荷转移分子的双光子吸收Two-photonAbsorption.PDFVIP

2011 年第 69 卷 化 学 学 报 Vol. 69, 2011 第 20 期, 2499～2504 ACTA CHIMICA SINICA No. 20, 2499～2504 ·研究论文· 三腈基呋喃推拉型电荷转移分子的双光子吸收 吉 彦a 钱 鹰*,a 周志强b 崔一平b (a 东南大学化学化工学院 南京 211189) (b 东南大学先进光子学中心 南京 210096) 摘要 根据双光子吸收效应与分子之间“构效”关系, 设计四种 D-π-A 推拉偶极型电荷转移分子, 采用 AM1 方法计算 出分子三阶极化率, 筛选出具有潜在三阶非线性光学活性分子 2-(3-腈基-(3-(4-(二甲胺基)苯乙烯基)-5,5-二甲环己基-2- 烯) 甲基)-5,5-二甲基呋喃-2-烯)丙二腈(CFM). 首次在温和条件下使酮羰基与 TCF (2-(3-腈基-4,5,5-三甲基呋喃-2-烯)丙 二腈) 的活泼甲基通过 Knoevenagel 反应合成出目标分子. 通过非线性透过率法研究了 CFM 的双光子吸收性质, 采用 Ti:Sapphire 激光器在 800 nm, 150 fs 激光激发下测得了 CFM 的双光子吸收截面σ2, 在 DMF 溶剂中达到 104.29 GM, 在 CH2Cl2 溶剂中达到 78.22 GM. CFM 具有较强的双光子吸收特性和光限幅效应. 关键词 三阶极化率; Knoevenagel 反应; 双光子吸收; 推拉型分子 Two-photon Absorption of a Push-pull Type Intramolecular Charge Transfer Molecule Including Tricyanofuran Ji, Yana Qian, Ying*,a Zhou, Zhiqiangb Cui, Yipingb a ( School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189) (b Advanced Photonics Center , Southeast University, Nanjing 210096) Abstract Four D-π-A push-pull type charge transfer molecules were designed basing on the relationship between two-photon absorption and the structure. AM1 method was used to calculate the three-order po- larizabilities of the four molecules and the molecule CFM (2-(3-cyano-(3-(4-(dimethyl-amino)styryl)- 5,5-dimethylcyclohe