基于三维网状TiO2骨架层的钙钛矿太阳电池研究-可再生能源与清洁能源专业论文.docx

华北电力大学硕士学位论文摘 华北电力大学硕士学位论文 摘 要 在钙钛矿太阳电池中，骨架层的作用是接受钙钛矿光吸收层中光生激发态的导 带电子，并将其传输至导电电极，其吸附钙钛矿的能力和电子输运性能是决定电池 能量转换效率的关键因素。三维网状结构的薄膜具有比表面积大、骨架结构丰富且 薄膜内部孔隙体积较大的特征，将其做为钙钛矿电池中的骨架层，有利于钙钛矿的 吸附和电子的传输。 本文采用光聚合诱导相分离的方法和旋涂镀膜的工艺，制备了具有三维网状结 构的Ti02薄膜。通过调节旋涂转速调节薄膜厚度，厚度越大时，电荷的分离与注入 发生的程度越大，但相应的载流子复合程度也越大，开路电压减小，当转速为 3000r／min时电池效率最大。通过增加旋涂次数来增加骨架层的层数，骨架层层数 越多，厚度增大，载流子复合越严重，降低了短路电流和开路电压， 1层时电池效 率最大。通过调节前驱体溶液中光单体POGTA的比例，比例越大，薄膜中孔道结 构越丰富，电池内部载流子复合逐渐降低，短路电流有逐渐增大的趋势， POGTA胛B为0．7时电池效率达到最大。 关键词：三维网状Ti02；钙钛矿；光伏性能；太阳电池 万方数据 华北电力大学硕士学位论文Abstract 华北电力大学硕士学位论文 Abstract In perovskite solar cell，the scaffold layer plays the role of absorbing the photo—generated electrons from perovskite．and transporting to electrode．ne ability of absorbing perovskite and electron transporting are the key factors to determine the photoelectric conversion efficiency of perovskite solar cell．The three-dimensional web—like structured film might be much suitable for perovskite solar cell．The porous structure may provide a larger specific surface area for perovskite adsorption，and the interconnected web—like structure Can benefit the electron transport． In this work．the Ti02 films谢m three-dimensional web-like porous structure were prepared by the photo polymerization-induced phase separation method integrated with蹿妇coating process． By,．ajusting the speed of sp证∞a恼喀出e film出iclcl撼姆w罄xljgsted．When the film is tllicker．the separation and injection of the charge is mol呛,the short-circuit current density increases，the open-circuit voltage decreases，and the solar cell’S efficiency reach the maximum when the spin coating Speed is 3000r／rain．By adjusting the times of spin coating，the layer number was adjusted．As the layer number getting more，the charge carder rebombines more，SO the short—circuit current density and open-circuit voltage decrease，the solar cell’s efficiency reach the maximum when the layer number is 1．By increasing the ratio of POGTA，the porous structure getting richer,the charge carrier rebombines less，and the s