基于阳极氧化原位制备LDHs功能薄膜的工艺及性能研究-化学工程与技术专业论文.docx

万方数据 万方数据 Abst Abstract Title: STUDY ON TECHNOLOGY AND CHARACTERISTIC OF IN-SITU PREPARATION OF LDHs FILM BASED ON ANODIC OXIDATIONS Major: Chemical Engineering and Technology Name: Yu YANG Signature: Supervisor: Prof. Baozhong DU Signature: Abstract LDHs is a typical anionic laminar chemical compound, which is accumulated layer upon layer by laminate with positive electricity and layer anions with negative charge. The binding affinity between subject layer board and guest anion include electrostatic interactions, hydrogen bond, van der Waals’ force, etc. Laminate metal element is diversification and layer spacing can change. Interlayer anion is diversification and interchangeability. These characteristics gave it the characteristics which as functional materials. Therefore, LDHs has been widely used in many areas, such as catalysis, adsorption, electrochemistry, medicine, farm chemicals, magnetic and Military material, etc. At present, the study on LDHs as power functional materials is relatively perfection, but the study on LDHs as film functional materials is less. So preparing LDHs into film has broad prospects. It can be used as superhydrophobic corrosion resistant material, membrane catalytic materials，battery and electrode materials, optical materials and magnetic materials, etc. In recent years, the methods of preparation LDHs film mainly are physical film technologys, such as colloid deposition technology, spinning coating technology, etc. And the study on in-situ synthesis LDHs film focuses on Al substrate. In this report, composing LDHs film on Fe, Al, Zn template by in-situ synthesis. It has many advantages, such as simple synthesis process, product distribution and small particles, firmly combined with the matrix and it’s difficult to falling, etc. Metal template can provide M2+, M3+ source for the reaction. It’s an energy saving method. Composed Ni/Fe-LDHs/Fe film based on