碳复合硅酸钴锂的溶剂热合成及其储锂问题分析【毕业设计】.docVIP

- PAGE I - （20 届） 本科毕业设计 碳复合硅酸钴锂的溶剂热合成及其储锂问题分析 Solvothermal Synthesis of Carbon Composite Lithium Cobalt Silicate and Its Lithium Storage Properties 所在学院 专业班级 化学 学生姓名 学号 指导教师 职称 完成日期 年 月 碳复合硅酸钴锂的溶剂热合成及其储锂问题分析 PAGE 4 PAGE 21 摘　要 【摘要】以硬碳球为模板采用水热法合成的方法来制备球形Li2CoSiO4 正极材料，并对获得的Li2CoSiO4 正极材料在一系列不同的温度下进行烧结处理。运用X 射线粉末衍射和红外光谱分析对材料的物相进行表征，并进行电化学性能测试。用红外光谱分析材料的结构特征和表面吸附物质后发现，用空气煅烧的球形Li2CoSiO4尤其是800 ℃煅烧制备的球形Li2CoSiO4，组装的电池的电化学性能要远远好过用氮气保护下煅烧的材料。此外, 交流阻抗测试还表明用空气煅烧的球形Li2CoSiO4材料电化学阻抗比氮气保护下煅烧的材料小。 【关键词】水热法；碳复合Li2CoSiO4；电化学；充放电循环 Solvothermal Synthesis of Carbon Composite Lithium Cobalt Silicate and Its Lithium Storage Properties Abstract 【ABSTRACT】Spherical Li2CoSiO4 cathode materials is synthesized by solvothermal method with hard carbon spherule as template. The as-prepared Li2CoSiO4 was heat-treated at different temperatures and atmospheres. The phase purity and crystallinity of carbon composite lithium colbalt silicate were characterized by X-ray diffraction (XRD) and infrared spectroscopy (IR). The electrochemical performance was evaluated by electrochemical techniques. Observed by IR and charge-discharge methods, it is found that compound obtained at 800 ℃ in air shows the best lithium storage properties among all the samples. The impurities in the compounds calcined at vacuum probably should be responsible for the poor electrochemical results. Besides, Li2CoSiO4 achieved by heattreatment in air exhibits lower impedance than that obtained in vacuum. It indicates that it is better to prepare Li2CoSiO4 in air to be a promising cathode materials for lithium ion batteries. 【KEYWORDS】Hydrothermal method; Carbon composite Li2CoSiO4; Electrochemical properties; Charge and discharge cycles 目　录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc292621705 摘　要 PAGEREF _Toc292621705 \h II HYPERLINK \l _Toc292621706 Abstract PAGEREF _Toc292621706 \h III HYPERLINK \l _To