轻质镁基金属有机框架材料的合成与结构研究【毕业设计】.docVIP

- PAGE I - （20 届） 本科毕业设计 轻质镁基金属有机框架材料的合成与结构研究 The syntheses and structures of lightweight Mg-based metal-organic framework materials 所在学院 专业班级 应用化学 学生姓名 学号 指导教师 职称 完成日期 年 月 轻质镁基金属有机框架材料的合成与结构研究 PAGE 2 PAGE 1 摘要 【摘要】：随着科学的发展，人们逐渐发现，以新型阳离子、阴离子及中性配体形成的有机金属有机框架MOFs具有孔隙率高、孔结构可控、比表面积大、化学性质稳定、制备过程简单等优点，并能多方面的应用于选择性催化、分子识别、可逆性主客体分子(离子)交换、超高纯度分离、生物传导材料、光电材料、磁性材料和芯片等新材料开发。合成新的轻质镁基金属有机框架材料，并研究它们的性质及应用，对晶体化学发展有着重要意义。我们采用六水硝酸镁和2-氨基对苯二甲酸，通过溶剂热法合成了镁配合物，并对其进行了红外光谱测试，荧光测试，单晶X射线衍射。单晶X射线衍射表明，镁基化合物晶体，[(Me2NH2)2Mg3O(NH2-BDC)3(H2O)3]·9H2O，属P6(3)/mmc空间群，晶胞参数：a= 14.0181(11)?，b = 14.0181(11)?，c = 17.9089(15)?，α=90o，β=90o，γ=120o，Z=2，V=3047.7(4)?3，F(000)=1505，R1 = 0.3787, wR2 = 0.5057。 【关键词】：金属有机框架；镁基化合物；合成；晶体结构 The syntheses and structures of lightweight Mg-based metal-organic framework materials Abstract 【ABSTRACT】 With the development of science, people gradually found to novel cationic, anionic and neutral organic ligands to form metal-organic framework (MOFs), which have high porosity, controllable pore structure, surface area, chemical stability, and simple preparation. MOFs can be applied in selective catalysis, molecular recognition, reversible host-guest molecules (ions) exchange, ultra-high purity separation, bio-conducting material, optical materials, magnetic materials and chips and other new materials. The synthesis of new lightweight magnesium based metal organic framework materials, and study of their properties and applications are of great significance for crystal chemistry. We synthesized a magnesium complex, [(Me2NH2)2Mg3O(NH2-BDC)3(H2O)3]·9H2O, by using of magnesium nitrate hexahydrate and 2-amino- p-phthalic acid under solvothermal reaction. This compound was characterized by infrared spectroscopy, fluorescence measurements, single crystal X-raydiffraction. Single crystal X-ray diffraction sh