手性樟脑酸类金属有机框架材料的合成与结构研究【毕业设计】.docVIP

- PAGE I - （20 届） 本科毕业设计 手性樟脑酸类金属有机框架材料的合成与结构研究 Synthesis and Structure Study of Metal-organic Framework with Chiral Camphor Acid 所在学院 专业班级 应用化学 学生姓名 学号 指导教师 职称 完成日期 年 月 性樟脑酸类金属有机框架材料的合成与结构研究 PAGE II PAGE 21 摘 要 【摘要】金属有机框架材料（简称MOFS）是一种新型的多孔材料，因其具有多孔性、比表面积大、合成方便、骨架规模大小可变以及可根据目标要求做化学修饰、结构丰富等优点，现已在气体吸附、催化、光电材料等领域受到人们的广泛关注。本论文旨在利用手性樟脑酸与金属离子组装成具有新颖结构的金属有机框架材料。在试验中，采用手性樟脑酸和金属钙离子以1:1配位通过水热法合成得到了新型的金属有机框架材料，对得到的晶体进行X射线衍射分析，并对其键长键角进行了分析。另外对其进行了热重表征，所得热重数据显示该晶体具有很强的热稳定性。单晶衍射结果表明，该晶体属单斜晶系，P2（1）/c空间群，晶胞参数：a = 14.0312(10) ?3，b = 19.0062(6) ?3，c = 17.4587(13) ?3 ，α = 90 o，β = 94.486(9) o，γ = 90 o，Z=1，V=4641.6(5) ?3，F(000)= 2625，R1 = 0.0924, ωR2 = 0.2409。 【关键词】 樟脑酸 ；手性 ；金属有机框架；晶体结构 Synthesis and Structure Study of Metal-organic Framework with Chiral Camphor Acid Abstract 【ABSTRACT】Metal organic framework material (referred to as MOFS) is a new type of porous material, because of its high altitude of the specific surface area, synthetic convenience, the variable frame size and can be chemically modified according to the objectives and requirements, structure, rich, etc., has been?in the gas adsorption, catalysis, optical materials and other areas of attention by people.?This paper aims to use a chiral camphor acid with metal ions assemble into novel structures of metal-organic framework materials.?In the study, the use of camphor acid and calcium ions in 1:1 metal ligand synthesized by hydrothermal method a new type of metal organic framework materials, crystals obtained by X-ray diffraction analysis, and the bond length bond angle were analysis.?In addition its characterization showed that the thermal re-crystal has a strong thermal stability.?Diffraction results show that the crystal is monoclinic, P2(1 )/ c space group, unit cell parameters: a = 14.0312(10) ?3, b = 19.0062(6) ?3 , c = 17.4587(13) ?3, α = 90 o, β = 94.486(9) o,γ = 90 o, Z=1, V=4641.