Nafion膜电化学制备有序燃料电池铂电极研究.docVIP

PAGE 毕业设计(论文) 题 目 Nafion膜电化学制备有序燃料电池铂电极研究 学生姓名 专业班级 所在院系　　　　　环境与化学工程学院　　　　　 指导教师 职 称　　 教 授 　　 所在单位 环境与化学工程学院 教研室主任 　 完成日期 摘 要 燃料电池是一种将储存在燃料和氧化剂中的化学能，通过催化剂的作用，使氢与氧发生化学反应，等温、高效、无污染地转化为电能的发电装置，其反应过程不涉及到燃烧，能量转化率可高达80％，实际使用效率是普通内燃机的2倍以上。本文的主要研究内容就是利用电化学方法制备nafion修饰电极铂有序化，因为这样可以提高燃料电池效率，实现高效节能。因为全球都在不断地使用能源，对于某些一次能源马上就要枯竭，对新能源的要求已经迫在眉睫。本文对nafion膜上的铂有序化研究为进一步提高能源利用率有深远的影响。 本文通过电化学方法如直流电沉积，循环伏安，计时电位等方法对nafion修饰电极进行电沉积。由于nafion膜具有选择透过性，膜内传质可以看做是分子扩散，因此在沉积过程中，效果表现比较缓慢，需要大量的时间投入。然后对制备的修饰电极进行物理和化学的表征，主要是循环伏安法以及扫描电镜，观察它的有序情况，及其表面形貌。 本文还通过利用改变实验条件方法来电沉积，例如时间，温度等方式，之后对不同条件下的电极进行比较。 关键字:修饰电极 电沉积 有序化 铂沉积 nafion膜 Abstract The fuel cell is a chemical stored in the fuel and oxidizer, so that making a chemical reaction between hydrogen and oxygen by a catalytic role, such as temperature, efficient, pollution-free electricity generating device. Its reaction does not involve combustion, energy conversion rate of up to 80%, the actual use efficiency is more than 2 times the ordinary internal combustion engine. The main research content of this paper is that by Electrochemical method making preparation of Nafion modified electrode platinum ordering, because it can improve the efficiency of fuel cells to achieve energy efficient. Because the world is in use of energy, for some of the primary energy is soon depleted, and the requirements of the new energy around the corner. Nafion membrane platinum ordering to further improve energy efficiency has a profound impact on it. This article says that nafion modified electrode is electrodeposited by electrochemical methods such as electrochemical deposition, cyclic voltammetry, chronopotentiometry method. Since Nafion membrane with selective permeability, the membrane mass transfer can be looked as a molecular diffusion in the deposition process, the effect is relatively slow performance, requires a lot of time investment. Then we