含电解质溶液相平衡计算-化学工程专业论文.docxVIP

万方数据 万方数据 The phase equilibrium calculation of solution containing electrolyte ABSTRACT The electrolyte solution widely exist in industrial processes, life science and nature, for example the Extraction and distillation of salting out with salt bath and desalination membrane desalination process , The development and utilization of salt lake resources, so the thermodynamic properties research of electrolyte solution has important theoretical significance and value in industry. Organic solution system containing salt appeared in the process of many chemical industry , for example: the extractive distillation, Received widely attention due to salt effect undermine its constant boiling, other like the heat pump technology, there is a kind of working medium is LiBr - H2O - CH3OH, also have many similar working medium, so to study thermodynamic properties of the solution containing organic and salt system has important significance for salt effect and distillation separation. Based on phase equilibrium problems for several different types of systems containing electrolytes, puts forward several new calculation method and a new thermodynamic model. 1. Based on the gibbs can minimize the method to calculate phase equilibrium principle ，sea water and alkaline water system which the phase behavior and phase number are unknown . Combinated minimizing gibbs free energy method and the genetic algorithm, established one step mathematical model for calculating of the phase behavior and composition. 2. Using the principle of Henrys law and dissolution equilibrium thermodynamics, established mathematical model to calculate KCl - HCl - NaCl - H2O three- phase equilibrium, and applied genetic algorithm to the optimal solution in the process of solving calculation. In view of the uniquac model cant be used well in the organic solution containing salt application problems,so this work put forward a new extended uniquac model, the influence of salt concentration in organic phase activit