过渡金属硼化物和硫化物的光谱研究-物理化学(含化学物理)专业论文.docxVIP

摘要【3】NiS自由基的光谱研究用Ni针放电产生Ni原子与H2S反应产生NiS自由基，在超声射流条件下得到了在15500—17200cmo范围内的激光诱导荧光激发谱。15个振动谱带归属为【15．65】3nl加’=0—4)一X3写(U”=O)，【l5．69】3∑i(U’=0—4)一X3写(U”2o)，和【15．81】3nI加’=0—4)一X3∑i0”=o)-个电子跃迁序列，光谱分析得到了这三个电子态的光谱常数。通过激光诱导荧光色散谱的研究，获得了基态的振动常数。我们还得到了这些跃迁在无碰撞下的跃迁寿命。在光谱数据和跃迁寿命的基础上，我们对这三个电子态的电子组态进行了讨论。关键词；过渡金属化合物，放电，激光诱导荧光激发谱，激光诱导荧光色散谱。UAbsttactAbstractThisthesispresentstheexperimentalstudiesonthelaser-inducedfluorescence(LIF)spectraofthethree3dtransition-metalCoandNiSulfurandBoride．TheNiB，CoSandNiSmoleculeswereproducedbyreactionofsputteredmetalatomswithsmallmoleculegasundersupersonicjetcooledcondition．Theelectronicstructureandchemicalbondingofeachmoleculewasdiscussed．ThemainresultsaresummarizedasfoIlows：【1】Thelaser-inducedfluorescenceexcitationspectraofjet．cooledNiBradicalhavebeenrecordedintheenergyrangeoff9000-22100cm。1．Elevenbandshavebeenassignedtothe[20．77]2YI．X2∑+transitionsystemforthefirsttime．Thedispersedfluorescencespectrarelatedtomostofthesebandshavebeeninvestigated，vibrationallyexcitedlevelsofthegroundelectronicstate，withV¨upto6，havebeenobserved．Inaddition，thelifetimesforalmostalltheobservedbandshavealsobeenmeasured．[21TheLaser-inducedfluorescenceexcitationspectraofjet—cooledCoSmoleculeshavebeenrecordedintheenergyrangeof15200-22600cm。．Eighttransitionprogressionshavebeenassigned，therearefivetransitionprogressionsassignedfromthegroundstateintheenergyrangeof15200-19100cm～，andthreetransitionprogressionsassignedfromtheAstateintheenergyof20100-22600cm～．Identifiyeightnewexcitedstatesforthefirsttimeandeveryexcitedstatehavebeendiscussed．Thedispersedfluorescencespectrarelatedtomostofthesebandshavebeeninvestigated，vibrationallyexcitedlevelsofthegroundelectronicstateandtheAstatehavebeenobserved．Inaddition，thelifetimesforalmostalltheobservedbandshavealsobeenmeasured．[3]Thelaser-inducedfluorescenceexcitationspectrumofjet．cooledNiSmoleculeshavebeenrecordedintheenergyrangeof15500—17200cm～．FiReenbandshavebeenassignedasthreetransitionprogressions：【15．65】3Hl0’=0—4)一X3∑i(U’’=O)，111Abstraet【