含氮 氧配体的配合物合成 表征及性能研究-无机化学专业论文.docxVIP

合物 11 是单核小分子配合物，在该配合物中发生了酰基化的原位反应。配合物 12 是单 核小分子配合物，通过两个相邻的卟啉分子之间弱的 π-π 作用形成二连体结构。配合物 9 具有 Zigzag 链结构，沿三个轴展示方形孔穴结构，羽翼型孔结构，多边形孔结构。配 合物 9 显示出良好的荧光性能，以配合物 9 为催化剂，进行了苯乙烯环氧化催化实验， 结果显示出配合物 9 具有一定的催化性能，并且可以重复使用。 关键词：吡啶羧酸，卟啉，晶体结构，荧光性质 IV Abstract The self-assembly coordination polymers pay much attention because of recently focused on the networking ability of the diverse Stacking patterns and topology structures, which are potentially able to work as in catalysis, nonlinear optics, ion exchange, gas storage, magnetism and molecular recognition.We summarize the research of pyridinecarboxylate and porphyrin coordination polymers and present the synthesis, characterization of the coordination polymers, the main results as follows: First, we synthesize eight coordination complexs constructed by pyridinecarboxylate ligand , bridging ligand and transition metal ions: [Cd(2,4-pydc)(2,2’-bpy)(H2O)]·3(H2O) (1),[Cd2(2,4-pydc)(phen)4](NO3)2·4(H2O) (2),[Mn2(2,4-pydc)2(bpe)(H2O)6]·(H2O) (3),[Mn2 (2.4-pydc)2(2,2’-bpy)2(H2O)2]·4(H2O) (4),[Zn(2,4-pydc)(phen)2]·7.5(H2O) (5),[Co(2,4-pydc) (2,2’-bpy)2]·5.5(H2O) (6)，｛[Cu(2,4-pydc)(bpp)(H2O)]·3.5(H2O)｝n (7)and｛[Zn(2,3-pydc)(bp p)]·4(H2O)｝n (8) (2,4-pydcH = 2,4-pyridinecarboxylate, 2,3-pydcH = 2,3-pyridinecarboxylate, 2,2’-bpy = 2,2’-bipyridyl ,phen = 1,10-phenanthroline, bpe = 1,2-bis(4-pyridyl)ethane, bpp = 1,3-bis (4-pyridyl)propane) They have been characterized by elemental analysis, IR, thermal analysis, X-ray diffraction analysis and the fluoresent properties of complex 1, 2 ,5, 8 are measured in the solid state at room temperature. Complex 1-4 are the dinuclear complexs. Complex 1 is connected by the packing π–π intentions between 2,2’-bpy to shows one-dimensional chain and is connected by hydrogen bondings and the packing π–π intentions to form three-dimensional wing network. Complex 2 is connected by the packing π–π intentions between phen to shows one-dimensional chain and is connected by hydrogen bondings and the packing π–π intent