利用噻吩丙二酸修饰玻碳电极快速检测苏丹红-食品科学.PDF

※分析检测 食品科学 2010, Vol. 31, No. 16 233 1 1 2 高愿军 ，张永峰 ，许光日 (1.郑州轻工业学院食品与生物工程学院，河南 郑州 450002 ；2.河南科技学院化学与化工学院，河南 新乡 453003) 利用电化学聚合法制备 3- 噻吩丙二酸(3-TPA)修饰玻碳电极。利用循环伏安法研究苏丹红在 3-TPA 修饰玻 碳电极上的电化学行为，得出预富集时间、pH 值、扫描速率及扫描范围因素对该修饰电极检测苏丹红的影响。在 -5 -3 最佳条件下，利用差分脉冲伏安法得出在2.0 ×10 ～1.3 ×10 mol/L 浓度范围内苏丹红Ⅰ响应电流与其浓度对数呈 良好的线性关系，相关系数r=0.996 ，检测限为4.8 × 10-6mol/L 。辣椒粉、辣椒酱加标回收率分别为99.9% 和 99.4% ，相对标准偏差(n=3) 分别为 0.25% 和 0.21% 。另外，对苏丹红Ⅰ氧化还原机理进行了初步的探讨。 ：3 - 噻吩丙二酸；苏丹红；差分脉冲伏安法；修饰电极 Fast Determination of Sudan Dyes Using Poly(3-Thiophenemalonic Acid) Modified Glassy Carbon Electrode 1 1 2 GAO Yuan-jun ，ZHANG Yong-feng ，XU Guang-ri (1. College of Food and Biological Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, China； 2. School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China) Abstract ：Poly(3-thiophenemalonic acid)(3-TPA) modified glassy carbon electrode was prepared by electrochemical polymerization, and the electrochemical behavior of Sudan dyes was studied on the modified electrode using cyclic voltammetric method. The effects of preconcentration time, pH value of buffer solution and scan rate and range were also studied using differential pulse voltammetry in order to determine their optimal values. Under the optimize conditions, the modified electrode -5 -3 showed a linear response over the Sudan Ⅰconcentration range from 2.0 × 10 to 1.3 × 10 mol/L, with a correla