规整孔道限制的纳米银粒子可控组装 表征及催化性能研究-物理化学专业论文.docxVIP

AbstractAbstract Abstract Abstract Junming Sun(Physical C铡stry) Directed by Pro￡)(inhe Bao Througout the last decMes，nanocatalysis has long been paid much attentions due to its considerable contribmions to industry．To explore nanosize effect in catalysis，one has to be able to synthesize monodispersed metal nanoparticles(e．g．， silver)with high thermal stabilities，which has been proved to be extremely difficult in practice．Although some feasible routes have been developed to synthesize protected metal nanoparticles，it is difficult to prevent those obtained metal nanoparticles from sintering during the high-temperature reactions．Recently, due to their higher surface areas，uniform mesostrueture and tunable pore size ete．， the ordered mesoporous materials have initiated the intensive research of inclusion c蛐stry,which is featured with the assemblage of metal，metal oxide， organometal，as well as semiconductors，inside the channels of mesoporous inorganic materials， Current work maillly focused on the fabrication of monodispersed metal (siZver)nanoparticles within the mesoporous silica materials晰m tunable pore·size．These mesoporous silica trapped metal nanoparticles have unique physical／chemical and．most importantly,catalytic pmpenies．The details ale as follows：(1)By freely tuning the reaction compositions，a temperature-induced phase transformation,from a swollen inverse hexagonal phase(H2)to a swollen lamellal phase(k)and then to a swollen normal micelles phase(LO，is set up in the alkane(from heptane to dodecane)／P123／water／TEOS quadm-eomponent system,d沁cted by which，corresponding complex silica materials，such觞 mesoporous llano—fibres，multilamellar vesicles(MLvs)and mesocellular foams Abstract(MCFs)，are Abstract (MCFs)，are obtained，(2)By controlling initial reaction temperatures，alkanes with different chain length(C5·C16)have been used鹳swelling agents to the continuous pore size expansion of highly ordered SBA-1 5．For the first time，the pore size of higray ordered SBA-15 wa